Literature DB >> 24779407

Dinitrogen splitting and functionalization in the coordination sphere of rhenium.

Isabel Klopsch1, Markus Finger, Christian Würtele, Bastian Milde, Daniel B Werz, Sven Schneider.   

Abstract

[ReCl3(PPh3)2(NCMe)] reacts with pincer ligand HN(CH2CH2PtBu2)2 (HPNP) to five coordinate rhenium(III) complex [ReCl2(PNP)]. This compound cleaves N2 upon reduction to give rhenium(V) nitride [Re(N)Cl(PNP)], as the first example in the coordination sphere of Re. Functionalization of the nitride ligand derived from N2 is demonstrated by selective C-N bond formation with MeOTf.

Entities:  

Year:  2014        PMID： 24779407     DOI： 10.1021/ja502759d

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

1.  Effects of N2 Binding Mode on Iron-Based Functionalization of Dinitrogen to Form an Iron(III) Hydrazido Complex.

Authors:  Sean F McWilliams; Eckhard Bill; Gudrun Lukat-Rodgers; Kenton R Rodgers; Brandon Q Mercado; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2018-06-29       Impact factor: 15.419

Review 2.  Activation of Dinitrogen by Polynuclear Metal Complexes.

Authors:  Devender Singh; William R Buratto; Juan F Torres; Leslie J Murray
Journal:  Chem Rev       Date:  2020-05-04       Impact factor: 60.622

3.  Rhenium-Mediated Conversion of Dinitrogen and Nitric Oxide to Nitrous Oxide.

Authors:  Lukas Alig; Kim A Eisenlohr; Yaroslava Zelenkova; Sven Rosendahl; Regine Herbst-Irmer; Serhiy Demeshko; Max C Holthausen; Sven Schneider
Journal:  Angew Chem Int Ed Engl       Date:  2021-12-02       Impact factor: 16.823

4.  Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species.

Authors:  Markus G Scheibel; Josh Abbenseth; Markus Kinauer; Frank W Heinemann; Christian Würtele; Bas de Bruin; Sven Schneider
Journal:  Inorg Chem       Date:  2015-07-20       Impact factor: 5.165

5.  Mechanism of Chemical and Electrochemical N2 Splitting by a Rhenium Pincer Complex.

Authors:  Brian M Lindley; Richt S van Alten; Markus Finger; Florian Schendzielorz; Christian Würtele; Alexander J M Miller; Inke Siewert; Sven Schneider
Journal:  J Am Chem Soc       Date:  2018-06-19       Impact factor: 15.419

6.  Facile conversion of ammonia to a nitride in a rhenium system that cleaves dinitrogen.

Authors:  Gannon P Connor; Daniel Delony; Jeremy E Weber; Brandon Q Mercado; Julia B Curley; Sven Schneider; James M Mayer; Patrick L Holland
Journal:  Chem Sci       Date:  2022-03-04       Impact factor: 9.825

7.  Photoelectrochemical Conversion of Dinitrogen to Benzonitrile: Selectivity Control by Electrophile- versus Proton-Coupled Electron Transfer.

Authors:  Maximilian Fritz; Severine Rupp; Ciara I Kiene; Sesha Kisan; Joshua Telser; Christian Würtele; Vera Krewald; Sven Schneider
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-18       Impact factor: 16.823

8.  Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum-dinitrogen complexes: unique behavior of ferrocene moiety as redox active site.

Authors:  Shogo Kuriyama; Kazuya Arashiba; Kazunari Nakajima; Hiromasa Tanaka; Kazunari Yoshizawa; Yoshiaki Nishibayashi
Journal:  Chem Sci       Date:  2015-04-20       Impact factor: 9.825

9.  Selectivity of tungsten mediated dinitrogen splitting vs. proton reduction.

Authors:  Bastian Schluschaß; Josh Abbenseth; Serhiy Demeshko; Markus Finger; Alicja Franke; Christian Herwig; Christian Würtele; Ivana Ivanovic-Burmazovic; Christian Limberg; Joshua Telser; Sven Schneider
Journal:  Chem Sci       Date:  2019-09-24       Impact factor: 9.825
  9 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.