Literature DB >> 24777066

Ordered alignment of a one-dimensional π-conjugated nickel bis(dithiolene) complex polymer produced via interfacial reactions.

Ryota Matsuoka1, Ryota Sakamoto, Tetsuya Kambe, Kenji Takada, Tetsuro Kusamoto, Hiroshi Nishihara.   

Abstract

A liquid-liquid interfacial synthesis using 1,2,4,5-benzenetetrathiol and nickel(II) ions produced a thin black film of a π-conjugated polymer featuring the nickel bis(dithiolene) motif. Its ordered structure was not originally identified due to its amorphicity; however, it was observed to align regularly on a highly oriented pyrolytic graphite substrate using scanning tunnelling microscopy.

Entities:  

Year:  2014        PMID： 24777066     DOI： 10.1039/c4cc02022g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

1.  Bis(dipyrrinato)metal(ii) coordination polymers: crystallization, exfoliation into single wires, and electric conversion ability.

Authors:  Ryota Matsuoka; Ryojun Toyoda; Ryota Sakamoto; Mizuho Tsuchiya; Ken Hoshiko; Tatsuhiro Nagayama; Yoshiyuki Nonoguchi; Kunihisa Sugimoto; Eiji Nishibori; Tsuyoshi Kawai; Hiroshi Nishihara
Journal:  Chem Sci       Date:  2015-02-26       Impact factor: 9.825
  1 in total

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