Literature DB >> 24772061

Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins.

Yiyang Liu1, Kelly E Kim1, Myles B Herbert1, Alexey Fedorov1, Robert H Grubbs1, Brian M Stoltz1.   

Abstract

A highly efficient palladium-catalyzed decarbonylative dehydration reaction of carboxylic acids is reported. This method transforms abundant and renewable even-numbered natural fatty acids into valuable and expensive odd-numbered alpha olefins. Additionally, the chemistry displays a high functional group tolerance. The process employs low loading of palladium catalyst and proceeds under solvent-free and relatively mild conditions.

Entities:  

Keywords:  decarbonylative dehydration; fatty acids; large scale process; linear alpha olefins; palladium; renewable feedstocks

Year:  2014        PMID： 24772061      PMCID： PMC3998208          DOI： 10.1002/adsc.201301109

Source DB:  PubMed          Journal:  Adv Synth Catal        ISSN： 1615-4150            Impact factor:   5.837


  6 in total

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6.  A mild and efficient protocol for the conversion of carboxylic acids to olefins by a catalytic decarbonylative elimination reaction.

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Journal:  Chem Commun (Camb)       Date:  2004-02-18       Impact factor: 6.222
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2.  Organic chemistry. Rh-catalyzed C-C bond cleavage by transfer hydroformylation.

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3.  Alkene Synthesis by Photocatalytic Chemoenzymatically Compatible Dehydrodecarboxylation of Carboxylic Acids and Biomass.

Authors:  Vu T Nguyen; Viet D Nguyen; Graham C Haug; Hang T Dang; Shengfei Jin; Zhiliang Li; Carsten Flores-Hansen; Brenda S Benavides; Hadi D Arman; Oleg V Larionov
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4.  Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (-)-Aspewentins A, B, and C.

Authors:  Yiyang Liu; Scott C Virgil; Robert H Grubbs; Brian M Stoltz
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5.  Bimetallic Cooperative Catalysis for Decarbonylative Heteroarylation of Carboxylic Acids via C-O/C-H Coupling.

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6.  A donor-acceptor complex enables the synthesis of E-olefins from alcohols, amines and carboxylic acids.

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Journal:  Chem Sci       Date:  2021-04-05       Impact factor: 9.825
  6 in total

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