Literature DB >> 24758330

Cu-catalyzed C(sp³)-H bond activation reaction for direct preparation of cycloallyl esters from cycloalkanes and aromatic aldehydes.

Jincan Zhao1, Hong Fang, Jianlin Han, Yi Pan.   

Abstract

Cu-catalyzed dehydrogenation-olefination and esterification of C(sp(3))-H bonds of cycloalkanes with TBHP as an oxidant has been developed. The reaction involves four C-H bond activations and gives cycloallyl ester products directly from cycloalkanes and aromatic aldehydes.

Entities:  

Year:  2014        PMID： 24758330     DOI： 10.1021/ol5009119

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes.

Authors:  Ba L Tran; Matthias Driess; John F Hartwig
Journal:  J Am Chem Soc       Date:  2014-11-24       Impact factor: 15.419

Review 2.  Cross-dehydrogenative coupling for the intermolecular C-O bond formation.

Authors:  Igor B Krylov; Vera A Vil'; Alexander O Terent'ev
Journal:  Beilstein J Org Chem       Date:  2015-01-20       Impact factor: 2.883

3.  Cascade alkylarylation of substituted N-allylbenzamides for the construction of dihydroisoquinolin-1(2H)-ones and isoquinoline-1,3(2H,4H)-diones.

Authors:  Ping Qian; Bingnan Du; Wei Jiao; Haibo Mei; Jianlin Han; Yi Pan
Journal:  Beilstein J Org Chem       Date:  2016-02-17       Impact factor: 2.883
  3 in total

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