Literature DB >> 24740697

CO/C-H as an acylating reagent: a palladium-catalyzed aerobic oxidative carbonylative esterification of alcohols.

Lu Wang1, Yanxia Wang, Chao Liu, Aiwen Lei.   

Abstract

A palladium-catalyzed oxidative carbonylative esterification of a variety of functionalized alcohols under base- and ligand-free conditions has been demonstrated. A CO/olefin combination was utilized as the acylating reagent with O2 as a benign oxidant. Notably, the scope of the substrate alcohols has been greatly broadened.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alcohols; esterification; oxidation; palladium; synthetic methods

Year:  2014        PMID: 24740697     DOI: 10.1002/anie.201400612

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

1.  Oxalyl amide assisted palladium-catalyzed synthesis of pyrrolidones via carbonylation of γ-C(sp3)-H bonds of aliphatic amine substrates.

Authors:  Chao Wang; Li Zhang; Changpeng Chen; Jian Han; Yingming Yao; Yingsheng Zhao
Journal:  Chem Sci       Date:  2015-05-19       Impact factor: 9.825

  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.