Literature DB >> 24730649

A porous metal-organic framework with dynamic pyrimidine groups exhibiting record high methane storage working capacity.

Bin Li1, Hui-Min Wen, Hailong Wang, Hui Wu, Madhusudan Tyagi, Taner Yildirim, Wei Zhou, Banglin Chen.   

Abstract

We have realized a new porous metal-organic framework UTSA-76a with pyrimidine groups on the linker, exhibiting high volumetric methane uptake of ~260 cm(3) (STP) cm(-3) at 298 K and 65 bar, and record high working capacity of ~200 cm(3) (STP) cm(-3) (between 5 and 65 bar). Such exceptionally high working capacity is attributed to the central "dynamic" pyrimidine groups within UTSA-76a, which are capable of adjusting their orientations to optimize the methane packing at high pressure, as revealed by computational studies and neutron scattering experiments.

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Year:  2014        PMID： 24730649     DOI： 10.1021/ja501810r

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  17 in total

1.  Modification of a nitrocellulose membrane with cellulose nanofibers for enhanced sensitivity of lateral flow assays: application to the determination of Staphylococcus aureus.

Authors:  Rui Hua Tang; Li Na Liu; Su Feng Zhang; Ang Li; Zedong Li
Journal:  Mikrochim Acta       Date:  2019-11-22       Impact factor: 5.833

2.  A microporous metal-organic framework with naphthalene diimide groups for high methane storage.

Authors:  Yingxiang Ye; Rui-Biao Lin; Hui Cui; Ali Alsalme; Wei Zhou; Taner Yildirim; Zhangjing Zhang; Shengchang Xiang; Banglin Chen
Journal:  Dalton Trans       Date:  2019-07-03       Impact factor: 4.390

3.  Methane storage in flexible metal-organic frameworks with intrinsic thermal management.

Authors:  Jarad A Mason; Julia Oktawiec; Mercedes K Taylor; Matthew R Hudson; Julien Rodriguez; Jonathan E Bachman; Miguel I Gonzalez; Antonio Cervellino; Antonietta Guagliardi; Craig M Brown; Philip L Llewellyn; Norberto Masciocchi; Jeffrey R Long
Journal:  Nature       Date:  2015-10-26       Impact factor: 49.962

4.  The influence of the enantiomeric ratio of an organic ligand on the structure and chirality of metal-organic frameworks.

Authors:  Iván Burneo; Kyriakos C Stylianou; Inhar Imaz; Daniel Maspoch
Journal:  Chem Commun (Camb)       Date:  2014-11-18       Impact factor: 6.222

5.  Microporous metal-organic framework with dual functionalities for highly efficient removal of acetylene from ethylene/acetylene mixtures.

Authors:  Tong-Liang Hu; Hailong Wang; Bin Li; Rajamani Krishna; Hui Wu; Wei Zhou; Yunfeng Zhao; Yu Han; Xue Wang; Weidong Zhu; Zizhu Yao; Shengchang Xiang; Banglin Chen
Journal:  Nat Commun       Date:  2015-06-04       Impact factor: 14.919

6.  Pentiptycene-Based Luminescent Cu (II) MOF Exhibiting Selective Gas Adsorption and Unprecedentedly High-Sensitivity Detection of Nitroaromatic Compounds (NACs).

Authors:  Minghui Zhang; Liangliang Zhang; Zhenyu Xiao; Qinhui Zhang; Rongming Wang; Fangna Dai; Daofeng Sun
Journal:  Sci Rep       Date:  2016-02-09       Impact factor: 4.379

7.  Organic-inorganic supramolecular solid catalyst boosts organic reactions in water.

Authors:  Pilar García-García; José María Moreno; Urbano Díaz; Marta Bruix; Avelino Corma
Journal:  Nat Commun       Date:  2016-02-25       Impact factor: 14.919

8.  A functionalized metal-organic framework decorated with O- groups showing excellent performance for lead(ii) removal from aqueous solution.

Authors:  Caixia Yu; Zhichao Shao; Hongwei Hou
Journal:  Chem Sci       Date:  2017-09-18       Impact factor: 9.825

9.  A computational study of CH4 storage in porous framework materials with metalated linkers: connecting the atomistic character of CH4 binding sites to usable capacity.

Authors:  Ehud Tsivion; Jarad A Mason; Miguel I Gonzalez; Jeffrey R Long; Martin Head-Gordon
Journal:  Chem Sci       Date:  2016-03-29       Impact factor: 9.825

10.  MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc-MOF for CH4, O2, and CO2 Storage.

Authors:  Dalal Alezi; Youssef Belmabkhout; Mikhail Suyetin; Prashant M Bhatt; Łukasz J Weseliński; Vera Solovyeva; Karim Adil; Ioannis Spanopoulos; Pantelis N Trikalitis; Abdul-Hamid Emwas; Mohamed Eddaoudi
Journal:  J Am Chem Soc       Date:  2015-10-07       Impact factor: 15.419
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