Literature DB >> 24729461

Iridium-catalyzed enantioselective C-H alkylation of ferrocenes with alkenes using chiral diene ligands.

Takanori Shibata1, Tsubasa Shizuno.   

Abstract

The first catalytic and enantioselective C-H alkylation of ferrocene derivatives with various alkenes was achieved. A cationic iridium complex, having a chiral diene ligand, and an isoquinolyl moiety as a directing group are essential for regioselective and enantioselective C-H bond activation.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CH activation; alkylation; enantioselectivity; iridium; synthetic methods

Year:  2014        PMID： 24729461     DOI： 10.1002/anie.201402518

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  6 in total

1.  Kinetic Resolution of Benzylamines via Palladium(II)-Catalyzed C-H Cross-Coupling.

Authors:  Kai-Jiong Xiao; Ling Chu; Gang Chen; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2016-06-10       Impact factor: 15.419

2.  Enantioselective remote meta-C-H arylation and alkylation via a chiral transient mediator.

Authors:  Hang Shi; Alastair N Herron; Ying Shao; Qian Shao; Jin-Quan Yu
Journal:  Nature       Date:  2018-06-18       Impact factor: 49.962

3.  Electrochemically driven regioselective C-H phosphorylation of group 8 metallocenes.

Authors:  Hao Zheng; Chang-Hui Liu; Shi-Yu Guo; Gu-Cheng He; Xiang-Ting Min; Bo-Chao Zhou; Ding-Wei Ji; Yan-Cheng Hu; Qing-An Chen
Journal:  Nat Commun       Date:  2022-06-17       Impact factor: 17.694

4.  Enantioselective C-H Olefination of α-Hydroxy and α-Amino Phenylacetic Acids by Kinetic Resolution.

Authors:  Kai-Jiong Xiao; Ling Chu; Jin-Quan Yu
Journal:  Angew Chem Int Ed Engl       Date:  2016-01-22       Impact factor: 15.336

5.  Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes.

Authors:  Zhong-Jian Cai; Chen-Xu Liu; Qiang Wang; Qing Gu; Shu-Li You
Journal:  Nat Commun       Date:  2019-09-13       Impact factor: 14.919

6.  Thiocarbonyl-enabled ferrocene C-H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical.

Authors:  Santhivardhana Reddy Yetra; Zhigao Shen; Hui Wang; Lutz Ackermann
Journal:  Beilstein J Org Chem       Date:  2018-06-25       Impact factor: 2.883
  6 in total

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