Literature DB >> 24706156

[4+2+2] Cycloaddition catalyzed by a new cationic rhodium-bisphosphine monooxide complex.

Gino Martin R Canlas1, Scott R Gilbertson.   

Abstract

A rhodium-BozPHOS based complex is reported. This complex is competent in catalyzing the [4+2+2] cycloisomerization of cyclooctatrienes in moderate to good yields. The X-ray crystal structure of this complex is reported, along with formation of both bicyclic and tricyclic cyclooctatrienes.

Entities:  

Year:  2014        PMID： 24706156     DOI： 10.1039/c4cc01320d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Cu-catalyzed carboboration of acetylene with Michael acceptors.

Authors:  Tairan Cheng; Boxiang Liu; Rui Wu; Shifa Zhu
Journal:  Chem Sci       Date:  2022-06-08       Impact factor: 9.969

2.  Selective Synthesis of Cyclooctanoids by Radical Cyclization of Seven-Membered Lactones: Neutron Diffraction Study of the Stereoselective Deuteration of a Chiral Organosamarium Intermediate.

Authors:  Xavier Just-Baringo; Jemma Clark; Matthias J Gutmann; David J Procter
Journal:  Angew Chem Int Ed Engl       Date:  2016-09-07       Impact factor: 15.336

3.  A rational pre-catalyst design for bis-phosphine mono-oxide palladium catalyzed reactions.

Authors:  Yining Ji; Hongming Li; Alan M Hyde; Qinghao Chen; Kevin M Belyk; Katrina W Lexa; Jingjun Yin; Edward C Sherer; R Thomas Williamson; Andrew Brunskill; Sumei Ren; Louis-Charles Campeau; Ian W Davies; Rebecca T Ruck
Journal:  Chem Sci       Date:  2017-01-19       Impact factor: 9.825

4.  A thiocyanopalladation/carbocyclization transformation identified through enzymatic screening: stereocontrolled tandem C-SCN and C-C bond formation.

Authors:  G Malik; R A Swyka; V K Tiwari; X Fei; G A Applegate; D B Berkowitz
Journal:  Chem Sci       Date:  2017-10-03       Impact factor: 9.825

Review 5.  Acetylene in Organic Synthesis: Recent Progress and New Uses.

Authors:  Vladimir V Voronin; Maria S Ledovskaya; Alexander S Bogachenkov; Konstantin S Rodygin; Valentine P Ananikov
Journal:  Molecules       Date:  2018-09-24       Impact factor: 4.411
  5 in total

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