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Literature DB >> 24686489

The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)·e(-) as an electron donor.

Ye Ji Kim¹, Sun Min Kim, Hideo Hosono, Jung Woon Yang, Sung Wng Kim.

Abstract

The scalable pinacol coupling reaction is realized utilizing the inorganic electride [Ca2N](+)·e(-) as an electron donor in organic solvents. The bond cleavages of the [Ca2N](+) layers by methanol play a vital role in transferring anionic electrons to electrophilic aldehydes, accompanying the formation of Ca(OMe)2 and ammonia.

Entities: Chemical Species

Year: 2014 PMID： 24686489 DOI： 10.1039/c4cc00802b

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

5 in total

1. Two dimensional inorganic electride-promoted electron transfer efficiency in transfer hydrogenation of alkynes and alkenes.

Authors: Ye Ji Kim; Sun Min Kim; Eun Jin Cho; Hideo Hosono; Jung Woon Yang; Sung Wng Kim
Journal: Chem Sci Date: 2015-04-13 Impact factor: 9.825

2. Metal-to-Semiconductor Transition and Electronic Dimensionality Reduction of Ca₂N Electride under Pressure.

Authors: Hu Tang; Biao Wan; Bo Gao; Yoshinori Muraba; Qin Qin; Bingmin Yan; Peng Chen; Qingyang Hu; Dongzhou Zhang; Lailei Wu; Mingzhi Wang; Hong Xiao; Huiyang Gou; Faming Gao; Ho-Kwang Mao; Hideo Hosono
Journal: Adv Sci (Weinh) Date: 2018-09-01 Impact factor: 16.806

The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)·e(-) as an electron donor.

1. Two dimensional inorganic electride-promoted electron transfer efficiency in transfer hydrogenation of alkynes and alkenes.

2. Metal-to-Semiconductor Transition and Electronic Dimensionality Reduction of Ca₂N Electride under Pressure.

3. Essential role of hydride ion in ruthenium-based ammonia synthesis catalysts.

4. Comparison Between Electride Characteristics of Li₃@B₄₀ and Li₃@C₆₀.

5. Non-Oxidized Bare Metal Nanoparticles in Air: A Rational Approach for Large-Scale Synthesis via Wet Chemical Process.

The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)·e(-) as an electron donor.

1. Two dimensional inorganic electride-promoted electron transfer efficiency in transfer hydrogenation of alkynes and alkenes.

2. Metal-to-Semiconductor Transition and Electronic Dimensionality Reduction of Ca2N Electride under Pressure.

3. Essential role of hydride ion in ruthenium-based ammonia synthesis catalysts.

4. Comparison Between Electride Characteristics of Li3@B40 and Li3@C60.

5. Non-Oxidized Bare Metal Nanoparticles in Air: A Rational Approach for Large-Scale Synthesis via Wet Chemical Process.

2. Metal-to-Semiconductor Transition and Electronic Dimensionality Reduction of Ca₂N Electride under Pressure.

4. Comparison Between Electride Characteristics of Li₃@B₄₀ and Li₃@C₆₀.