Literature DB >> 24679827

Chromatographic separation of selenium and arsenic: A potential (72)Se/(72)As generator.

Donald E Wycoff1, Matthew D Gott1, Anthony J DeGraffenreid1, Ryan P Morrow1, Nebiat Sisay1, Mary F Embree2, Beau Ballard3, Michael E Fassbender3, Cathy S Cutler2, Alan R Ketring2, Silvia S Jurisson4.   

Abstract

An anion exchange method was developed to separate selenium and arsenic for potential utility in a (72)Se/(72)As generator. The separation of the daughter (72)As from the (72)Se parent is based on the relative acid-base behavior of the two oxo-anions in their highest oxidation states. At pH 1.5, selenate is retained on strongly basic anion exchange resin as HSeO4(-) and SeO4(2-), while neutral arsenic acid, H3AsO4, is eluted.
Copyright © 2014 Elsevier B.V. All rights reserved.

Entities:  

Keywords:  As-72; Ion exchange; Radionuclide generator; Se-72

Mesh:

Substances:

Year:  2014        PMID: 24679827      PMCID: PMC4030290          DOI: 10.1016/j.chroma.2014.03.033

Source DB:  PubMed          Journal:  J Chromatogr A        ISSN: 0021-9673            Impact factor:   4.759


  16 in total

Review 1.  Radioarsenic from a portable (72)Se/(72)As generator: a current perspective.

Authors:  B Ballard; F M Nortier; E R Birnbaum; K D John; D R Phillips; M E Fassbender
Journal:  Curr Radiopharm       Date:  2012-07

2.  Isomeric cross-section ratio for the formation of 73m,gSe in various nuclear processes.

Authors: 
Journal:  Phys Rev C Nucl Phys       Date:  1988-08

3.  Cyclotron isotopes and radiopharmaceuticals--XXVIII. Production of potassium-38 for myocardial perfusion studies.

Authors:  R M Lambrecht; T Hara; B M Gallagher; A P Wolf; A Ansari; H Atkins
Journal:  Int J Appl Radiat Isot       Date:  1978-11

Review 4.  PET imaging with ⁸⁹Zr: from radiochemistry to the clinic.

Authors:  Melissa A Deri; Brian M Zeglis; Lynn C Francesconi; Jason S Lewis
Journal:  Nucl Med Biol       Date:  2012-09-19       Impact factor: 2.408

5.  Novel radiochemical separation of arsenic from selenium for 72Se/72As generator.

Authors:  Ewelina Chajduk; Katarzyna Doner; Halina Polkowska-Motrenko; Aleksander Bilewicz
Journal:  Appl Radiat Isot       Date:  2012-02-01       Impact factor: 1.513

6.  Adsorption and separation behavior of yttrium and strontium in nitric acid solution by extraction chromatography using a macroporous silica-based adsorbent.

Authors:  Yuanlai Xu; Seong-Yun Kim; Tatsuya Ito; Kasane Nakazawa; Yoshihito Funaki; Tsutomu Tada; Keitaro Hitomi; Keizo Ishii
Journal:  J Chromatogr A       Date:  2012-09-16       Impact factor: 4.759

7.  Selenium-72 formation via nat Br(p,x) induced by 100 MeV protons: steps towards a novel 72Se/72As generator system.

Authors:  B Ballard; D Wycoff; E R Birnbaum; K D John; J W Lenz; S S Jurisson; C S Cutler; F M Nortier; W A Taylor; M E Fassbender
Journal:  Appl Radiat Isot       Date:  2012-02-01       Impact factor: 1.513

8.  Vascular imaging of solid tumors in rats with a radioactive arsenic-labeled antibody that binds exposed phosphatidylserine.

Authors:  Marc Jennewein; Matthew A Lewis; Dawen Zhao; Edward Tsyganov; Nikolai Slavine; Jin He; Linda Watkins; Vikram D Kodibagkar; Sean O'Kelly; Padmakar Kulkarni; Peter P Antich; Alex Hermanne; Frank Rösch; Ralph P Mason; Philip E Thorpe
Journal:  Clin Cancer Res       Date:  2008-03-01       Impact factor: 12.531

Review 9.  Iodine-124: a promising positron emitter for organic PET chemistry.

Authors:  Lena Koehler; Katherine Gagnon; Steve McQuarrie; Frank Wuest
Journal:  Molecules       Date:  2010-04-13       Impact factor: 4.411

10.  Highly specific PET imaging of prostate tumors in mice with an iodine-124-labeled antibody fragment that targets phosphatidylserine.

Authors:  Jason H Stafford; Guiyang Hao; Anne M Best; Xiankai Sun; Philip E Thorpe
Journal:  PLoS One       Date:  2013-12-19       Impact factor: 3.240

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  1 in total

1.  Trithiols and their arsenic compounds for potential use in diagnostic and therapeutic radiopharmaceuticals.

Authors:  Anthony J DeGraffenreid; Yutian Feng; Charles L Barnes; Alan R Ketring; Cathy S Cutler; Silvia S Jurisson
Journal:  Nucl Med Biol       Date:  2016-02-14       Impact factor: 2.408

  1 in total

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