Literature DB >> 24678029

Total synthesis of the putative structure of xylarinol B.

Atul A More1, Chepuri V Ramana.   

Abstract

The total synthesis of the putative structure of xylarinol B is described and the need to revise its structure is demonstrated. The central benzoxepine skeleton was constructed by employing a cobalt-mediated bimolecular [2+2+2] Reppe-Vollhardt alkyne cycloaddition reaction.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  chiral pool; cobalt; natural products; structure elucidation; total synthesis

Mesh：

Substances：

Year:  2014        PMID： 24678029     DOI： 10.1002/asia.201301647

Source DB:  PubMed          Journal:  Chem Asian J        ISSN： 1861-471X


  2 in total

Review 1.  Acetylene in Organic Synthesis: Recent Progress and New Uses.

Authors:  Vladimir V Voronin; Maria S Ledovskaya; Alexander S Bogachenkov; Konstantin S Rodygin; Valentine P Ananikov
Journal:  Molecules       Date:  2018-09-24       Impact factor: 4.411

2.  Air-Stable CpCoI-Phosphite-Fumarate Precatalyst in Cyclization Reactions: Comparing Different Methods of Energy Supply.

Authors:  Fabian Fischer; Marko Hapke
Journal:  European J Org Chem       Date:  2018-06-21
  2 in total

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