Literature DB >> 24676349

Copper-mediated trifluoromethylation of propargyl acetates leading to trifluoromethyl-allenes.

Yun-Long Ji1, Jun-Jie Kong, Jin-Hong Lin, Ji-Chang Xiao, Yu-Cheng Gu.   

Abstract

A copper-mediated trifluoromethylation of propargyl acetates with S-(trifluoromethyl)diphenylsulfonium triflate leading to trifluoromethylated allenes in moderate to excellent yields is described.

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Year:  2014        PMID： 24676349     DOI： 10.1039/c3ob42575d

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  3 in total

1.  Metal-catalyzed Decarboxylative Fluoroalkylation Reactions.

Authors:  Brett R Ambler; Ming-Hsiu Yang; Ryan A Altman
Journal:  Synlett       Date:  2016-12       Impact factor: 2.454

2.  Ligand-Controlled Regioselective Copper-Catalyzed Trifluoromethylation To Generate (Trifluoromethyl)allenes.

Authors:  Brett R Ambler; Santosh Peddi; Ryan A Altman
Journal:  Org Lett       Date:  2015-04-24       Impact factor: 6.005

3.  Iron-Catalyzed Cross-Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols.

Authors:  Daniels Posevins; Aitor Bermejo-López; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2021-09-02       Impact factor: 16.823
  3 in total

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