Literature DB >> 24661053

Palladium-catalyzed trifluoromethylthiolation of aryl C-H bonds.

Chunfa Xu1, Qilong Shen.   

Abstract

A method for monotrifluoromethylthiolation of arenes via palladium-catalyzed directed C-H bond activation was described. The reaction was compatible with a variety of functional groups. Initial mechanistic studies disclosed that the turnover limiting step of the catalytic cycle did not involve C-H activation.

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Year:  2014        PMID： 24661053     DOI： 10.1021/ol5006533

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  7 in total

1.  Visible-Light-Induced, Copper-Catalyzed Three-Component Coupling of Alkyl Halides, Olefins, and Trifluoromethylthiolate to Generate Trifluoromethyl Thioethers.

Authors:  Jian He; Caiyou Chen; Gregory C Fu; Jonas C Peters
Journal:  ACS Catal       Date:  2018-10-31       Impact factor: 13.084

2.  Three-Component Friedel-Crafts Transformations: Synthesis of Alkyl and Alkenyl Trifluoromethyl Sulfides and Alkenyl Iodides.

Authors:  Duc Chu; Jonathan A Ellman
Journal:  Org Lett       Date:  2022-04-08       Impact factor: 6.072

3.  Nickel-catalyzed trifluoromethylthiolation of Csp2-O bonds.

Authors:  Alexander B Dürr; Guoyin Yin; Indrek Kalvet; François Napoly; Franziska Schoenebeck
Journal:  Chem Sci       Date:  2015-10-30       Impact factor: 9.825

4.  When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides.

Authors:  Indrek Kalvet; Qianqian Guo; Graham J Tizzard; Franziska Schoenebeck
Journal:  ACS Catal       Date:  2017-01-31       Impact factor: 13.084

5.  Metal free C-3 chalcogenation (sulfenylation and selenylation) of 4H-pyrido[1,2-a]pyrimidin-4-ones.

Authors:  Prasanjit Ghosh; Gautam Chhetri; Sajal Das
Journal:  RSC Adv       Date:  2021-03-09       Impact factor: 3.361

6.  2-Diazo-1-phenyl-2-((trifluoromethyl)sulfonyl)ethan-1-one: Another Utility for Electrophilic Trifluoromethylthiolation Reactions.

Authors:  Zhongyan Huang; Kenta Okuyama; Chen Wang; Etsuko Tokunaga; Xiaorui Li; Norio Shibata
Journal:  ChemistryOpen       Date:  2016-01-28       Impact factor: 2.911

7.  Pd-Catalyzed Directed Thiocyanation Reaction by C-H Bond Activation.

Authors:  Mélissa Gao; Mu-Yi Chen; Xavier Pannecoucke; Philippe Jubault; Tatiana Besset
Journal:  Chemistry       Date:  2020-11-03       Impact factor: 5.236
  7 in total

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