Literature DB >> 24660960

Copper-mediated trifluoromethylthiolation of α-diazoesters.

Mingyou Hu1, Jian Rong, Wenjun Miao, Chuanfa Ni, Yongxin Han, Jinbo Hu.   

Abstract

A novel Cu-mediated trifluoromethylthiolation of diazo compounds has been developed that provides a convenient synthetic route for the efficient α-trifluoromethylthiolation of simple esters under mild reaction conditions. The reaction is typically carried out at room temperature, and water could be used to promote the reaction.

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Year:  2014        PMID: 24660960     DOI: 10.1021/ol500612n

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  Efficient Synthesis of β-CF3/SCF3-Substituted Carbonyls via Copper-Catalyzed Electrophilic Ring-Opening Cross-Coupling of Cyclopropanols.

Authors:  Yong Li; Zhishi Ye; Tabitha M Bellman; Teng Chi; Mingji Dai
Journal:  Org Lett       Date:  2015-04-17       Impact factor: 6.072

2.  Copper-catalyzed cyanothiolation to incorporate a sulfur-substituted quaternary carbon center.

Authors:  Yubing Huang; Xianwei Li; Xu Wang; Yue Yu; Jia Zheng; Wanqing Wu; Huanfeng Jiang
Journal:  Chem Sci       Date:  2017-08-15       Impact factor: 9.825

3.  Dual gold and photoredox catalysis: visible light-mediated intermolecular atom transfer thiosulfonylation of alkenes.

Authors:  Haoyu Li; Cuicui Shan; Chen-Ho Tung; Zhenghu Xu
Journal:  Chem Sci       Date:  2017-01-04       Impact factor: 9.825

  3 in total

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