| Literature DB >> 24651907 |
Mykola Tasinkevych1, Frédéric Mondiot, Olivier Mondain-Monval, Jean-Christophe Loudet.
Abstract
Colloidal particles dispersed in a partially ordered medium, such as a liquid crystal (LC) phase, disturb its alignment and are subject to elastic forces. These forces are long-ranged, anisotropic and tunable through temperature or external fields, making them a valuable asset to control colloidal assembly. The latter is very sensitive to the particle geometry since it alters the interactions between the colloids. We here present a detailed numerical analysis of the energetics of elongated objects, namely prolate ellipsoids, immersed in a nematic host. The results, complemented with qualitative experiments, reveal novel LC configurations with peculiar topological properties around the ellipsoids, depending on their aspect ratio and the boundary conditions imposed on the nematic order parameter. The latter also determine the preferred orientation of ellipsoids in the nematic field, because of elastic torques, as well as the morphology of particle aggregates.Year: 2014 PMID: 24651907 DOI: 10.1039/c3sm52708e
Source DB: PubMed Journal: Soft Matter ISSN: 1744-683X Impact factor: 3.679