Literature DB >> 24648167

A chiral thioxanthone as an organocatalyst for enantioselective [2+2] photocycloaddition reactions induced by visible light.

Rafael Alonso1, Thorsten Bach.   

Abstract

Thioxanthone 1, which was synthesized in a concise fashion from methyl thiosalicylate, exhibits a significant absorption in the visible light region. It allows for an efficient enantioselective catalysis of intramolecular [2+2] photocycloaddition reactions presumably by triplet energy transfer.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  cycloaddition; enantioselectivity; hydrogen bonds; organocatalysis; photochemistry

Year:  2014        PMID: 24648167     DOI: 10.1002/anie.201310997

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  40 in total

1.  Enantioselective Crossed Photocycloadditions of Styrenic Olefins by Lewis Acid Catalyzed Triplet Sensitization.

Authors:  Zachary D Miller; Byung Joo Lee; Tehshik P Yoon
Journal:  Angew Chem Int Ed Engl       Date:  2017-08-30       Impact factor: 15.336

2.  Enantioselective Excited-State Photoreactions Controlled by a Chiral Hydrogen-Bonding Iridium Sensitizer.

Authors:  Kazimer L Skubi; Jesse B Kidd; Hoimin Jung; Ilia A Guzei; Mu-Hyun Baik; Tehshik P Yoon
Journal:  J Am Chem Soc       Date:  2017-11-16       Impact factor: 15.419

3.  Asymmetric photoredox transition-metal catalysis activated by visible light.

Authors:  Haohua Huo; Xiaodong Shen; Chuanyong Wang; Lilu Zhang; Philipp Röse; Liang-An Chen; Klaus Harms; Michael Marsch; Gerhard Hilt; Eric Meggers
Journal:  Nature       Date:  2014-11-06       Impact factor: 49.962

4.  Enantioselective Photocatalytic [3 + 2] Cycloadditions of Aryl Cyclopropyl Ketones.

Authors:  Adrian G Amador; Evan M Sherbrook; Tehshik P Yoon
Journal:  J Am Chem Soc       Date:  2016-03-29       Impact factor: 15.419

5.  Enantioselective photochemistry through Lewis acid-catalyzed triplet energy transfer.

Authors:  Travis R Blum; Zachary D Miller; Desiree M Bates; Ilia A Guzei; Tehshik P Yoon
Journal:  Science       Date:  2016-12-16       Impact factor: 47.728

6.  Recent Advances in the Synthesis of Cyclobutanes by Olefin [2 + 2] Photocycloaddition Reactions.

Authors:  Saner Poplata; Andreas Tröster; You-Quan Zou; Thorsten Bach
Journal:  Chem Rev       Date:  2016-03-28       Impact factor: 60.622

Review 7.  Enantioselective synthesis of heterocyclic compounds using photochemical reactions.

Authors:  Norbert Hoffmann
Journal:  Photochem Photobiol Sci       Date:  2021-11-25       Impact factor: 3.982

8.  Bromine Radical Catalysis by Energy Transfer Photosensitization.

Authors:  Dian-Feng Chen; Cameron H Chrisman; Garret M Miyake
Journal:  ACS Catal       Date:  2020-01-30       Impact factor: 13.084

Review 9.  Chiral Photocatalyst Structures in Asymmetric Photochemical Synthesis.

Authors:  Matthew J Genzink; Jesse B Kidd; Wesley B Swords; Tehshik P Yoon
Journal:  Chem Rev       Date:  2021-10-04       Impact factor: 60.622

Review 10.  Recent Visible Light and Metal Free Strategies in [2+2] and [4+2] Photocycloadditions.

Authors:  Marina Sicignano; Ricardo I Rodríguez; José Alemán
Journal:  European J Org Chem       Date:  2021-06-10
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