| Literature DB >> 24643455 |
Dieter Enders1, Bianca A Stöckel, Andreas Rembiak.
Abstract
The first enantio- and chemoselective Brønsted-acid catalysed reduction of α-keto esters with catecholborane has been developed. The α-hydroxy esters were obtained under mild reaction conditions in virtually quantitative yields and excellent enantioselectivities. With slight modifications both enantiomers can be obtained without any loss of selectivity.Entities:
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Year: 2014 PMID： 24643455 DOI： 10.1039/c4cc00427b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222