Literature DB >> 24622767

Magnetic moments and exchange coupling in nitride clusterfullerenes Gd(x)Sc(3-x)N@C80 (x = 1-3).

A L Svitova1, Y Krupskaya, N Samoylova, R Kraus, J Geck, L Dunsch, A A Popov.   

Abstract

The magnetic properties of nitride clusterfullerenes GdxSc3-xN@C80 (x = 1-3) are studied as a function of the number of Gd atoms in the cluster. The intracluster interaction of the Gd ions in Gd2ScN@C80 and Gd3N@C80 is ferromagnetic with exchange constants of -1.2 K ± 0.1 K and -0.6 K ± 0.1 K, respectively. At 2 K, the magnetization curves exhibit noticeable deviations from the Heisenberg model pointing to a non-negligible anisotropy.

Entities:  

Year:  2014        PMID： 24622767     DOI： 10.1039/c3dt53367k

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  7 in total

1.  Enhancing T1 magnetic resonance imaging contrast with internalized gadolinium(III) in a multilayer nanoparticle.

Authors:  Valeria S Marangoni; Oara Neumann; Luke Henderson; Caterina C Kaffes; Hui Zhang; Runmin Zhang; Sandra Bishnoi; Ciceron Ayala-Orozco; Valtencir Zucolotto; James A Bankson; Peter Nordlander; Naomi J Halas
Journal:  Proc Natl Acad Sci U S A       Date:  2017-06-19       Impact factor: 11.205

2.  Selective arc-discharge synthesis of Dy2S-clusterfullerenes and their isomer-dependent single molecule magnetism.

Authors:  Chia-Hsiang Chen; Denis S Krylov; Stanislav M Avdoshenko; Fupin Liu; Lukas Spree; Ravi Yadav; Antonis Alvertis; Liviu Hozoi; Konstantin Nenkov; Aram Kostanyan; Thomas Greber; Anja U B Wolter; Alexey A Popov
Journal:  Chem Sci       Date:  2017-06-30       Impact factor: 9.825

3.  Magnetic anisotropy of endohedral lanthanide ions: paramagnetic NMR study of MSc2N@C80-Ih with M running through the whole 4f row.

Authors:  Y Zhang; D Krylov; M Rosenkranz; S Schiemenz; A A Popov
Journal:  Chem Sci       Date:  2015-01-28       Impact factor: 9.825

4.  The key energy scales of Gd-based metallofullerene determined by resonant inelastic x-ray scattering spectroscopy.

Authors:  Yu-Cheng Shao; L Andrew Wray; Shih-Wen Huang; Yi-Sheng Liu; Wang Song; Shangfeng Yang; Yi-De Chuang; Jinghua Guo; Way-Faung Pong
Journal:  Sci Rep       Date:  2017-08-15       Impact factor: 4.379

5.  Magnetization relaxation in the single-ion magnet DySc2N@C80: quantum tunneling, magnetic dilution, and unconventional temperature dependence.

Authors:  D S Krylov; F Liu; A Brandenburg; L Spree; V Bon; S Kaskel; A U B Wolter; B Büchner; S M Avdoshenko; A A Popov
Journal:  Phys Chem Chem Phys       Date:  2018-04-19       Impact factor: 3.676

6.  Single-Molecule Magnets DyM2 N@C80 and Dy2 MN@C80 (M=Sc, Lu): The Impact of Diamagnetic Metals on Dy3+ Magnetic Anisotropy, Dy⋅⋅⋅Dy Coupling, and Mixing of Molecular and Lattice Vibrations.

Authors:  Lukas Spree; Christin Schlesier; Aram Kostanyan; Rasmus Westerström; Thomas Greber; Bernd Büchner; Stanislav M Avdoshenko; Alexey A Popov
Journal:  Chemistry       Date:  2020-02-06       Impact factor: 5.236

7.  Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism.

Authors:  Ariane Brandenburg; Denis S Krylov; Alexander Beger; Anja U B Wolter; Bernd Büchner; Alexey A Popov
Journal:  Chem Commun (Camb)       Date:  2018-09-20       Impact factor: 6.222
  7 in total

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