Literature DB >> 24616170

Size-selective complexation and extraction of endohedral metallofullerenes with cycloparaphenylene.

Yusuke Nakanishi1, Haruka Omachi, Sanae Matsuura, Yasumitsu Miyata, Ryo Kitaura, Yasutomo Segawa, Kenichiro Itami, Hisanori Shinohara.   

Abstract

A new strategy for the non-chromatographic extraction of metallofullerenes from solutions of arc-processed raw soot is based on the size-selective complexation with cycloparaphenylene (CPP). [11]CPP has a high affinity for Mx @C82 (x=1, 2); for example, Gd@C82 can be selectively extracted from a fullerene mixture by the addition of [11]CPP. This approach should open new opportunities in metallofullerene chemistry, including for the bulk extraction of metallofullerenes.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  conjugation; cycloparaphenylenes; host-guest systems; macrocycles; metallofullerenes

Mesh：

Substances：

Year:  2014        PMID： 24616170     DOI： 10.1002/anie.201311268

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  11 in total

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Review 4.  Non-Chromatographic Purification of Endohedral Metallofullerenes.

Authors:  Zhiyong Wang; Haruka Omachi; Hisanori Shinohara
Journal:  Molecules       Date:  2017-04-29       Impact factor: 4.411

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Journal:  Chem Sci       Date:  2016-03-09       Impact factor: 9.825

Review 6.  The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs.

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Journal:  Front Chem       Date:  2019-10-09       Impact factor: 5.221

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8.  Carbon nanorings with inserted acenes: breaking symmetry in excited state dynamics.

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Journal:  Sci Rep       Date:  2016-08-10       Impact factor: 4.379

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Journal:  Nat Commun       Date:  2018-05-16       Impact factor: 14.919

10.  The importance of intramolecular conductivity in three dimensional molecular solids.

Authors:  Melissa L Ball; Boyuan Zhang; Tianren Fu; Ayden M Schattman; Daniel W Paley; Fay Ng; Latha Venkataraman; Colin Nuckolls; Michael L Steigerwald
Journal:  Chem Sci       Date:  2019-08-28       Impact factor: 9.825
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