Literature DB >> 24615766

Ruthenium/Imidazolylphosphine catalysis: hydrogenation of aliphatic and aromatic nitriles to form amines.

Svenja Werkmeister1, Kathrin Junge, Bianca Wendt, Anke Spannenberg, Haijun Jiao, Christoph Bornschein, Matthias Beller.   

Abstract

A convenient and efficient catalyst system for the hydrogenation of aliphatic nitriles towards the corresponding primary amines in high to excellent yields is presented. In addition, aromatic nitriles are reduced smoothly, too. The use of low catalyst loadings and molecular hydrogen make this protocol an attractive methodology.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  P,N ligands; amine; hydrogenation; nitrile; ruthenium

Mesh:

Substances:

Year:  2014        PMID: 24615766     DOI: 10.1002/chem.201303989

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  2 in total

1.  Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Polysilane/SiO2-Supported Palladium Catalyst under Continuous-Flow Conditions.

Authors:  Yuki Saito; Haruro Ishitani; Masaharu Ueno; Shū Kobayashi
Journal:  ChemistryOpen       Date:  2017-01-23       Impact factor: 2.911

2.  Magnesium-catalysed nitrile hydroboration.

Authors:  Catherine Weetman; Mathew D Anker; Merle Arrowsmith; Michael S Hill; Gabriele Kociok-Köhn; David J Liptrot; Mary F Mahon
Journal:  Chem Sci       Date:  2015-10-20       Impact factor: 9.825

  2 in total

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