Literature DB >> 24609409

Branched tetrasilane substituted phosphines - synthesis and characterisation of PhSi(SiiPr2)3P and {PhSi(SiMe2)3}2P14.

Michael Feierabend1, Carsten von Hänisch.   

Abstract

The branched trichlorotetrasilane PhSi(SiMe2Cl)3 reacts with P7(SiMe3)3 leading to formation of a new oligophosphane {PhSi(SiMe2)3}2P14 (1), which consists of two PhSi(SiMe2)3 substituted P7 norbornane units. The phosphatetrasila[1.1.1]pentane derivative PhSi(SiiPr2)3P (3) was obtained from the reaction of PhSi(SiiPr2Cl)3 (2) with Li3P.

Entities:  

Year:  2014        PMID： 24609409     DOI： 10.1039/c4cc00165f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Zintl superalkalis as building blocks of supersalts.

Authors:  G Naaresh Reddy; A Vijay Kumar; Rakesh Parida; Arindam Chakraborty; Santanab Giri
Journal:  J Mol Model       Date:  2018-10-05       Impact factor: 1.810

2.  Redox and Coordination Behavior of the Hexaphosphabenzene Ligand in [(Cp*Mo)2 (μ,η(6) :η(6) -P6 )] Towards the "Naked" Cations Cu(+) , Ag(+) , and Tl(.).

Authors:  Martin Fleischmann; Fabian Dielmann; Laurence J Gregoriades; Eugenia V Peresypkina; Alexander V Virovets; Sebastian Huber; Alexey Y Timoshkin; Gábor Balázs; Manfred Scheer
Journal:  Angew Chem Int Ed Engl       Date:  2015-09-04       Impact factor: 15.336
  2 in total

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