Literature DB >> 24601603

Palladium(II)-catalyzed direct regioselectively oxidative acylation of azobenzenes with toluene derivatives.

Hongyu Song1, Dong Chen, Chao Pi, Xiuling Cui, Yangjie Wu.   

Abstract

A highly efficient and practical procedure to acylazobenzene via Pd-catalyzed oxidative C-H bond activation from toluene has been developed. Various mono- and diacylazobenzene were afforded simultaneously in moderate to excellent yields for 33 examples. Toluene and its derivatives were served as potential and ideal acylation reagents. The mono- and diacylated products could be controlled by the oxidant loading.

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Year:  2014        PMID: 24601603     DOI: 10.1021/jo5000219

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  Direct Dehydrogenative Access to Unsymmetrical Phenones.

Authors:  Congjun Yu; Raolin Huang; Frederic W Patureau
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-19       Impact factor: 16.823

2.  H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers.

Authors:  Arun Maji; Amit Dahiya; Gang Lu; Trisha Bhattacharya; Massimo Brochetta; Giuseppe Zanoni; Peng Liu; Debabrata Maiti
Journal:  Nat Commun       Date:  2018-09-04       Impact factor: 14.919

  2 in total

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