Influence of the composition and removal characteristics of organic matter on heavy metal distribution in compost leachates.

Compost leachates were collected to investigate the influence of the composition and removal of volatile fatty acids (VFAs), humic-like substances (HSs), and dissolved organic nitrogen (DON) on heavy metal distribution during the leachate treatment process. The results showed that acetic and propionic acids accounted for 81.3 to 93.84% of VFAs, and that these acids were removed by the anaerobic-aerobic process. Humic- and fulvic-like substances were detected by excitation-emission matrix spectroscopy coupled with parallel factor analysis, and their content significantly decreased after the anaerobic and membrane treatments. DON in compost leachates ranged from 26.53 mg L(-1) to 919.46 mg L(-1), comprised of dissolved free amino acids and the protein-like matter bound to humic- and fulvic-like substances, and was removed by the aerobic process. Correlation analysis showed that Mn, Ni, and Pb were bound to VFAs and protein-, fulvic-, and humic-like substances in the leachates. Co was primarily bound to fulvic- and humic-like matter and inorganic sulfurs, whereas Cu, Zn, and Cd interacted with inorganic sulfur.