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Literature DB >> 24595745

Recent advances in asymmetric intra- and intermolecular halofunctionalizations of alkenes.

Yi An Cheng¹, Wesley Zongrong Yu, Ying-Yeung Yeung.

Abstract

This review seeks to provide coverage on recent advances in catalytic enantioselective halofunctionalization of alkenes. The aim is to give an overview of various reports, highlighting the new reaction types and strategies developed during the past two years. The scope and challenges of intra- and intermolecular reaction variants are discussed as well.

Entities: Chemical

Year: 2014 PMID： 24595745 DOI： 10.1039/c3ob42335b

Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876

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Cited

20 in total

1. Biomimetic Desymmetrization of a Carboxylic Acid.

Authors: Matthew T Knowe; Michael W Danneman; Sarah Sun; Maren Pink; Jeffrey N Johnston
Journal: J Am Chem Soc Date: 2018-02-05 Impact factor: 15.419

2. Catalytic Regio- and Enantioselective Haloazidation of Allylic Alcohols.

Authors: Frederick J Seidl; Chang Min; Jovan A Lopez; Noah Z Burns
Journal: J Am Chem Soc Date: 2018-11-12 Impact factor: 15.419

3. Reversing the Regioselectivity of Halofunctionalization Reactions through Cooperative Photoredox and Copper Catalysis.

Authors: Jeremy D Griffin; Cortney L Cavanaugh; David A Nicewicz
Journal: Angew Chem Int Ed Engl Date: 2017-01-20 Impact factor: 15.336

4. Enantioselective small molecule synthesis by carbon dioxide fixation using a dual Brønsted acid/base organocatalyst.

Authors: Brandon A Vara; Thomas J Struble; Weiwei Wang; Mark C Dobish; Jeffrey N Johnston
Journal: J Am Chem Soc Date: 2015-06-03 Impact factor: 15.419

5. Catalytic, Enantioselective Synthesis of Cyclic Carbamates from Dialkyl Amines by CO₂-Capture: Discovery, Development, and Mechanism.

Authors: Roozbeh Yousefi; Thomas J Struble; Jenna L Payne; Mahesh Vishe; Nathan D Schley; Jeffrey N Johnston
Journal: J Am Chem Soc Date: 2018-12-24 Impact factor: 15.419

Recent advances in asymmetric intra- and intermolecular halofunctionalizations of alkenes.

1. Biomimetic Desymmetrization of a Carboxylic Acid.

2. Catalytic Regio- and Enantioselective Haloazidation of Allylic Alcohols.

3. Reversing the Regioselectivity of Halofunctionalization Reactions through Cooperative Photoredox and Copper Catalysis.

4. Enantioselective small molecule synthesis by carbon dioxide fixation using a dual Brønsted acid/base organocatalyst.

5. Catalytic, Enantioselective Synthesis of Cyclic Carbamates from Dialkyl Amines by CO₂-Capture: Discovery, Development, and Mechanism.

Review 6. Catalytic Enantioselective Dihalogenation in Total Synthesis.

7. Enantioselective Aza-Sakurai Cyclizations: Dual Role of Thiourea as H-Bond Donor and Lewis Base.

Review 8. Catalytic, Stereoselective Dihalogenation of Alkenes: Challenges and Opportunities.

Review 9. Stereoselective Halogenation in Natural Product Synthesis.

10. Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics.