| Literature DB >> 24584582 |
Terrence J Udovic1, Motoaki Matsuo, Atsushi Unemoto, Nina Verdal, Vitalie Stavila, Alexander V Skripov, John J Rush, Hitoshi Takamura, Shin-ichi Orimo.
Abstract
Impedance measurements indicate that Na2B12H12 exhibits dramatic Na(+) conductivity (on the order of 0.1 S cm(-1)) above its order-disorder phase-transition at ≈529 K, rivaling that of current, solid-state, ceramic-based, Na-battery electrolytes. Superionicity may be aided by the large size, quasispherical shape, and high rotational mobility of the B12H12(2-) anions.Entities:
Year: 2014 PMID： 24584582 DOI： 10.1039/c3cc49805k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222