Room temperature Frenkel-Wannier-Mott hybridization of degenerate excitons in a strongly coupled microcavity.

Hybrid organic-inorganic polaritons are formed by the simultaneous strong coupling of two degenerate excitons and a microcavity photon at room temperature. Wannier-Mott and Frenkel excitons in spatially separated ZnO and 3,4,7,8-napthalene tetracarboxylic dianhydride (NTCDA) layers, respectively, placed in a single Fabry-Perot microcavity contribute to the interaction with the cavity. A Rabi splitting of (322±8)  meV between the upper and middle branches of the three branch polariton energy-momentum dispersion is observed. This is compared to only (224±22)  meV and (218±8)  meV Rabi splittings for NTCDA-only and ZnO-only reference cavities, respectively, and indicates that the excitonic component of the polariton is a Frenkel-Wannier-Mott hybrid. Unlike previous reports of hybrid polaritons, the mixing of the organic and inorganic eigenstates occurs independently of angle due to their energetic degeneracy, and can be tailored by adjusting the optical field distribution within the cavity.