| Literature DB >> 24574057 |
P Polińska1, C Gillig, J P Wittmer, J Baschnagel.
Abstract
Conformational properties of regular dendrimers and more general hyperbranched polymer stars with Gaussian statistics for the spacer chains between branching points are revisited numerically. We investigate the scaling for asymptotically long chains especially for fractal dimensions df = 3 (marginally compact) and df = 2.5 (diffusion limited aggregation). Power-law stars obtained by imposing the number of additional arms per generation are compared to truly self-similar stars. We discuss effects of weak excluded-volume interactions and sketch the regime where the Gaussian approximation should hold in dense solutions and melts for sufficiently large spacer chains.Entities:
Year: 2014 PMID: 24574057 DOI: 10.1140/epje/i2014-14012-7
Source DB: PubMed Journal: Eur Phys J E Soft Matter ISSN: 1292-8941 Impact factor: 1.890