Literature DB >> 24528003

Redox modulation of magnetic slow relaxation in a 4f-based single-molecule magnet with a 4d carbon-rich ligand.

Lucie Norel1, Min Feng, Kevin Bernot, Thierry Roisnel, Thierry Guizouarn, Karine Costuas, Stéphane Rigaut.   

Abstract

A ruthenium carbon-rich-based ligand that brings redox reversibility to a dysprosium-based single-molecule magnet is reported. Long-distance perturbation of the 4f ion is achieved upon oxidation, resulting in an overall enhancement of the magnetic slow relaxation.

Entities:  

Year:  2014        PMID: 24528003     DOI: 10.1021/ic403081y

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  1 in total

1.  Transition metal redox switches for reversible "on/off" and "slow/fast" single-molecule magnet behaviour in dysprosium and erbium bis-diamidoferrocene complexes.

Authors:  Courtney M Dickie; Alexander L Laughlin; Joshua D Wofford; Nattamai S Bhuvanesh; Michael Nippe
Journal:  Chem Sci       Date:  2017-10-02       Impact factor: 9.825

  1 in total

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