Literature DB >> 24527728

Planar chiral tetrasubstituted [2.2]paracyclophane: optical resolution and functionalization.

Yasuhiro Morisaki1, Masayuki Gon, Takahiro Sasamori, Norihiro Tokitoh, Yoshiki Chujo.   

Abstract

We achieved optical resolution of 4,7,12,15-tetrasubstituted [2.2]paracyclophane and subsequent transformation to planar chiral building blocks. An optically active propeller-shaped macrocyclic compound containing a planar chiral cyclophane core was synthesized, showing excellent chiroptical properties such as high fluorescence quantum efficiency and a large circularly polarized luminescence dissymmetry factor.

Entities:  

Year:  2014        PMID： 24527728     DOI： 10.1021/ja412197j

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  16 in total

1.  Enantiomerically Pure 5,13-Dicyano-9-oxa[7]helicene: Synthesis and Study.

Authors:  Riddhi Gupta; Trevor A Cabreros; Gilles Muller; Ashutosh V Bedekar
Journal:  European J Org Chem       Date:  2018-09-15

2.  Circularly Polarized Luminescence from Simple Organic Molecules.

Authors:  Esther M Sánchez-Carnerero; Antonia R Agarrabeitia; Florencio Moreno; Beatriz L Maroto; Gilles Muller; María J Ortiz; Santiago de la Moya
Journal:  Chemistry       Date:  2015-07-01       Impact factor: 5.236

3.  Design and Synthesis of New Circularly Polarized Thermally Activated Delayed Fluorescence Emitters.

Authors:  Sophie Feuillastre; Mathilde Pauton; Longhui Gao; Alaric Desmarchelier; Adrian J Riives; Damien Prim; Denis Tondelier; Bernard Geffroy; Gilles Muller; Gilles Clavier; Grégory Pieters
Journal:  J Am Chem Soc       Date:  2016-03-18       Impact factor: 15.419

Review 4.  Selected synthetic strategies to cyclophanes.

Authors:  Mukesh Eknath Shirbhate; Gopalkrushna T Waghule; Sambasivarao Kotha
Journal:  Beilstein J Org Chem       Date:  2015-07-29       Impact factor: 2.883

5.  Synthesis, optical properties, and helical self-assembly of a bivaline-containing tetraphenylethene.

Authors:  Hongkun Li; Xiaoyan Zheng; Huimin Su; Jacky W Y Lam; Kam Sing Wong; Shan Xue; Xuejiao Huang; Xuhui Huang; Bing Shi Li; Ben Zhong Tang
Journal:  Sci Rep       Date:  2016-01-13       Impact factor: 4.379

Review 6.  Regioselective Functionalization of [2.2]Paracyclophanes: Recent Synthetic Progress and Perspectives.

Authors:  Zahid Hassan; Eduard Spuling; Daniel M Knoll; Stefan Bräse
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-30       Impact factor: 15.336

7.  Enhancement of Chiroptical Responses of trans-Bis[(β-iminomethyl)naphthoxy]platinum(II) Complexes with Distorted Square Planar Coordination Geometry.

Authors:  Masahiro Ikeshita; Sho Furukawa; Takahiro Ishikawa; Kana Matsudaira; Yoshitane Imai; Takashi Tsuno
Journal:  ChemistryOpen       Date:  2022-01-31       Impact factor: 2.630

8.  Strong circularly polarized luminescence from the supramolecular gels of an achiral gelator: tunable intensity and handedness.

Authors:  Zhaocun Shen; Tianyu Wang; Lin Shi; Zhiyong Tang; Minghua Liu
Journal:  Chem Sci       Date:  2015-04-30       Impact factor: 9.825

9.  Direct Synthesis of Chiral Porphyrin Macrocyclic Receptors via Regioselective Nitration.

Authors:  Shaji Varghese; Bram Spierenburg; Anne Swartjes; Paul B White; Paul Tinnemans; Johannes A A W Elemans; Roeland J M Nolte
Journal:  Org Lett       Date:  2018-06-12       Impact factor: 6.005

Review 10.  [2.2]Paracyclophane-Based Chiral Platforms for Circularly Polarized Luminescence Fluorophores and Their Chiroptical Properties: Past and Future.

Authors:  Ken-Ichi Sugiura
Journal:  Front Chem       Date:  2020-10-29       Impact factor: 5.221
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