Hexane-1,6-di-ammonium hexa-fluoro-silicate.

The asymmetric unit of the title organic-inorganic molecular salt, C6H18N2 (2+)·SiF6 (2-), consists of one anion and one cation together with half of each of two cations and two anions located on inversion centres. The SiF6 (2-) octa-hedral anions are arranged to form sheets parallel to (011), which are linked into a three-dimensional network by the organic cations through N-H⋯F hydrogen bonds.

Related literature

For background to potential physical properties of alkyl­diammonium halogenometallate salts, see: Ouasri et al. (2003 ▶); Elyoubi et al. (2004 ▶). For the structures of related compounds, see: Jeghnou et al. (2005 ▶); Ouasri et al. (2012 ▶, 2013a ▶,b ▶); Rhandour et al. (2011 ▶); Elaoud et al. (1995 ▶).

Experimental

Crystal data

C6H18N2 2+·SiF6 2−

M = 260.31

Triclinic,

a = 5.8965 (2) Å

b = 13.6946 (5) Å

c = 14.4945 (5) Å

α = 91.379 (2)°

β = 92.797 (2)°

γ = 90.906 (2)°

V = 1168.53 (7) Å3

Z = 4

Mo Kα radiation

μ = 0.25 mm−1

T = 296 K

0.37 × 0.33 × 0.28 mm

Data collection

Bruker X8 APEX diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2009 ▶) T min = 0.686, T max = 0.747

29127 measured reflections

4760 independent reflections

3618 reflections with I > 2σ(I)

R int = 0.023

Refinement

R[F 2 > 2σ(F 2)] = 0.052

wR(F 2) = 0.159

S = 1.06

4760 reflections

274 parameters

H-atom parameters constrained

Δρmax = 0.46 e Å−3

Δρmin = −0.26 e Å−3

Data collection: APEX2 (Bruker, 2009 ▶); cell refinement: SAINT-Plus (Bruker, 2009 ▶); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012 ▶); software used to prepare material for publication: PLATON (Spek, 2009 ▶) and publCIF (Westrip, 2010 ▶).

Crystal structure: contains datablock(s) I. DOI: 10.1107/S1600536813034144/rz5101sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536813034144/rz5101Isup2.hkl

Additional supporting information: crystallographic information; 3D view; checkCIF report

C6H18N22+·SiF62−	Z = 4
Mr = 260.31	F(000) = 544
Triclinic, P1	Dx = 1.480 Mg m−3
a = 5.8965 (2) Å	Mo Kα radiation, λ = 0.71073 Å
b = 13.6946 (5) Å	Cell parameters from 4760 reflections
c = 14.4945 (5) Å	θ = 2.0–26.4°
α = 91.379 (2)°	µ = 0.25 mm−1
β = 92.797 (2)°	T = 296 K
γ = 90.906 (2)°	Block, colourless
V = 1168.53 (7) Å3	0.37 × 0.33 × 0.28 mm

Bruker X8 APEX diffractometer	4760 independent reflections
Radiation source: fine-focus sealed tube	3618 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.023
φ and ω scans	θmax = 26.4°, θmin = 2.0°
Absorption correction: multi-scan (SADABS; Bruker, 2009)	h = −7→7
Tmin = 0.686, Tmax = 0.747	k = −17→17
29127 measured reflections	l = −18→18

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.052	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.159	H-atom parameters constrained
S = 1.06	w = 1/[σ2(Fo2) + (0.0734P)2 + 1.0436P] where P = (Fo2 + 2Fc2)/3
4760 reflections	(Δ/σ)max < 0.001
274 parameters	Δρmax = 0.46 e Å−3
0 restraints	Δρmin = −0.26 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against all reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on all data will be even larger.

	x	y	z	Uiso*/Ueq
C1	0.4600 (7)	0.7541 (2)	0.9702 (2)	0.0601 (9)
H1A	0.2997	0.7367	0.9682	0.072*
H1B	0.5425	0.7018	1.0000	0.072*
C2	0.5353 (7)	0.7632 (3)	0.8734 (2)	0.0632 (9)
H2A	0.4561	0.8168	0.8443	0.076*
H2B	0.6965	0.7788	0.8755	0.076*
C3	0.4917 (8)	0.6720 (3)	0.8158 (2)	0.0773 (12)
H3A	0.3295	0.6585	0.8117	0.093*
H3B	0.5638	0.6180	0.8471	0.093*
C4	0.5760 (8)	0.6754 (3)	0.7179 (2)	0.0828 (12)
H4A	0.7366	0.6925	0.7221	0.099*
H4B	0.5608	0.6103	0.6902	0.099*
C5	0.4604 (8)	0.7437 (3)	0.6558 (2)	0.0739 (11)
H5A	0.4718	0.8083	0.6848	0.089*
H5B	0.3006	0.7254	0.6507	0.089*
C6	0.5433 (7)	0.7508 (2)	0.5600 (2)	0.0624 (9)
H6A	0.4661	0.8039	0.5292	0.075*
H6B	0.7043	0.7669	0.5642	0.075*
C7	0.0516 (6)	1.0370 (2)	0.2857 (2)	0.0523 (7)
H7A	−0.0151	1.0834	0.2432	0.063*
H7B	0.2133	1.0513	0.2925	0.063*
C8	−0.0506 (6)	1.0498 (2)	0.3775 (2)	0.0552 (8)
H8A	−0.2110	1.0330	0.3703	0.066*
H8B	−0.0383	1.1184	0.3959	0.066*
C9	0.0530 (6)	0.9906 (2)	0.45450 (19)	0.0552 (8)
H9A	0.0358	0.9217	0.4379	0.066*
H9B	0.2143	1.0058	0.4614	0.066*
C10	−0.0545 (6)	0.5465 (2)	0.21254 (19)	0.0497 (7)
H10A	−0.2183	0.5377	0.2075	0.060*
H10B	0.0104	0.4860	0.2339	0.060*
C11	0.0292 (6)	0.5675 (2)	0.11971 (19)	0.0524 (7)
H11A	0.1936	0.5724	0.1243	0.063*
H11B	−0.0279	0.6302	0.1003	0.063*
C12	−0.0417 (7)	0.4908 (3)	0.0471 (2)	0.0617 (9)
H12A	0.0139	0.4281	0.0672	0.074*
H12B	−0.2062	0.4864	0.0426	0.074*
N1	0.4970 (3)	0.84453 (16)	1.02554 (13)	0.0367 (5)
H1NB	0.4442	0.8948	0.9937	0.044*
H1NA	0.6449	0.8535	1.0388	0.044*
H1NC	0.4243	0.8402	1.0777	0.044*
N2	0.5073 (3)	0.66128 (16)	0.50333 (14)	0.0357 (5)
H2NA	0.5824	0.6126	0.5298	0.043*
H2NC	0.5580	0.6706	0.4473	0.043*
H2NB	0.3597	0.6463	0.4985	0.043*
N3	0.0159 (3)	0.93712 (15)	0.24637 (13)	0.0341 (5)
H3NA	0.0877	0.8948	0.2826	0.041*
H3NB	0.0703	0.9338	0.1902	0.041*
H3NC	−0.1320	0.9226	0.2426	0.041*
N4	0.0039 (3)	0.62479 (15)	0.28063 (13)	0.0326 (4)
H4NA	−0.0539	0.6104	0.3343	0.039*
H4NB	−0.0532	0.6808	0.2609	0.039*
H4NC	0.1542	0.6308	0.2880	0.039*
F1	0.3057 (2)	0.80063 (13)	0.34886 (10)	0.0471 (4)
F2	0.3060 (2)	0.77137 (12)	0.18810 (10)	0.0437 (4)
F3	0.5306 (3)	0.90186 (12)	0.25488 (13)	0.0553 (5)
F4	0.7096 (2)	0.76175 (13)	0.19650 (11)	0.0476 (4)
F5	0.7122 (3)	0.79006 (15)	0.35786 (11)	0.0560 (5)
F6	0.4882 (3)	0.66026 (12)	0.29172 (12)	0.0496 (4)
F7	0.2030 (2)	0.49066 (13)	0.42253 (11)	0.0483 (4)
F8	0.0188 (3)	0.62264 (11)	0.49428 (12)	0.0516 (4)
F9	−0.2025 (3)	0.49935 (13)	0.41489 (11)	0.0514 (4)
F10	0.0226 (3)	1.11843 (13)	−0.02764 (13)	0.0575 (5)
F11	−0.1963 (2)	1.02734 (14)	0.07661 (10)	0.0519 (5)
F12	0.2087 (2)	1.01509 (14)	0.08206 (10)	0.0505 (4)
Si1	0.50922 (10)	0.78157 (5)	0.27367 (5)	0.0328 (2)
Si2	0.0000	0.5000	0.5000	0.0339 (2)
Si3	0.0000	1.0000	0.0000	0.0370 (3)

	U11	U22	U33	U12	U13	U23
C1	0.084 (2)	0.0542 (19)	0.0415 (16)	−0.0097 (17)	0.0083 (15)	−0.0045 (14)
C2	0.081 (2)	0.064 (2)	0.0448 (17)	−0.0093 (18)	0.0126 (16)	−0.0058 (15)
C3	0.128 (4)	0.057 (2)	0.0463 (19)	−0.002 (2)	0.007 (2)	−0.0031 (16)
C4	0.118 (3)	0.081 (3)	0.050 (2)	0.025 (2)	0.005 (2)	−0.0012 (19)
C5	0.105 (3)	0.067 (2)	0.0488 (19)	0.016 (2)	−0.0007 (19)	−0.0104 (17)
C6	0.092 (3)	0.0506 (19)	0.0448 (17)	−0.0089 (17)	0.0047 (16)	−0.0023 (14)
C7	0.073 (2)	0.0411 (16)	0.0428 (16)	−0.0057 (14)	0.0037 (14)	0.0020 (12)
C8	0.076 (2)	0.0458 (17)	0.0431 (16)	0.0089 (15)	0.0005 (14)	−0.0075 (13)
C9	0.074 (2)	0.0551 (19)	0.0367 (15)	0.0095 (16)	0.0021 (14)	−0.0084 (13)
C10	0.0667 (19)	0.0424 (16)	0.0400 (15)	−0.0072 (14)	0.0086 (13)	−0.0043 (12)
C11	0.068 (2)	0.0513 (18)	0.0378 (15)	−0.0085 (15)	0.0098 (13)	−0.0074 (13)
C12	0.085 (2)	0.060 (2)	0.0407 (17)	−0.0171 (18)	0.0137 (16)	−0.0115 (14)
N1	0.0343 (11)	0.0477 (13)	0.0284 (10)	−0.0005 (9)	0.0031 (8)	0.0055 (9)
N2	0.0327 (11)	0.0439 (12)	0.0312 (10)	0.0027 (9)	0.0046 (8)	0.0050 (9)
N3	0.0349 (11)	0.0409 (12)	0.0267 (10)	0.0020 (9)	0.0030 (8)	0.0023 (8)
N4	0.0320 (10)	0.0375 (11)	0.0289 (10)	0.0021 (8)	0.0038 (8)	0.0032 (8)
F1	0.0376 (8)	0.0681 (11)	0.0373 (8)	0.0117 (7)	0.0124 (6)	0.0080 (7)
F2	0.0325 (8)	0.0626 (10)	0.0359 (8)	0.0011 (7)	−0.0024 (6)	0.0082 (7)
F3	0.0435 (9)	0.0435 (9)	0.0799 (12)	0.0011 (7)	0.0045 (8)	0.0161 (8)
F4	0.0340 (8)	0.0681 (11)	0.0431 (9)	0.0119 (7)	0.0149 (6)	0.0189 (8)
F5	0.0363 (8)	0.0857 (13)	0.0454 (9)	0.0008 (8)	−0.0084 (7)	0.0099 (9)
F6	0.0425 (9)	0.0421 (9)	0.0662 (11)	0.0062 (7)	0.0118 (7)	0.0212 (8)
F7	0.0371 (8)	0.0635 (11)	0.0468 (9)	0.0107 (7)	0.0178 (7)	0.0171 (8)
F8	0.0465 (9)	0.0389 (9)	0.0708 (11)	0.0031 (7)	0.0104 (8)	0.0149 (8)
F9	0.0358 (8)	0.0743 (12)	0.0443 (9)	−0.0001 (8)	−0.0040 (7)	0.0178 (8)
F10	0.0428 (9)	0.0582 (11)	0.0726 (12)	−0.0008 (8)	0.0034 (8)	0.0268 (9)
F11	0.0351 (8)	0.0858 (13)	0.0366 (8)	0.0119 (8)	0.0090 (6)	0.0158 (8)
F12	0.0311 (8)	0.0823 (13)	0.0380 (8)	−0.0017 (8)	−0.0052 (6)	0.0121 (8)
Si1	0.0246 (3)	0.0431 (4)	0.0318 (4)	0.0035 (3)	0.0040 (3)	0.0126 (3)
Si2	0.0250 (5)	0.0411 (6)	0.0368 (5)	0.0039 (4)	0.0067 (4)	0.0142 (4)
Si3	0.0244 (5)	0.0575 (7)	0.0298 (5)	0.0011 (4)	0.0022 (4)	0.0166 (4)

C1—N1	1.466 (4)	C11—H11B	0.9700
C1—C2	1.500 (4)	C12—C12ii	1.499 (6)
C1—H1A	0.9700	C12—H12A	0.9700
C1—H1B	0.9700	C12—H12B	0.9700
C2—C3	1.498 (5)	N1—H1NB	0.8900
C2—H2A	0.9700	N1—H1NA	0.8900
C2—H2B	0.9700	N1—H1NC	0.8900
C3—C4	1.527 (5)	N2—H2NA	0.8900
C3—H3A	0.9700	N2—H2NC	0.8900
C3—H3B	0.9700	N2—H2NB	0.8900
C4—C5	1.467 (5)	N3—H3NA	0.8900
C4—H4A	0.9700	N3—H3NB	0.8900
C4—H4B	0.9700	N3—H3NC	0.8900
C5—C6	1.499 (5)	N4—H4NA	0.8900
C5—H5A	0.9700	N4—H4NB	0.8900
C5—H5B	0.9700	N4—H4NC	0.8900
C6—N2	1.466 (4)	F1—Si1	1.6794 (15)
C6—H6A	0.9700	F2—Si1	1.6837 (15)
C6—H6B	0.9700	F3—Si1	1.6798 (17)
C7—N3	1.478 (3)	F4—Si1	1.6868 (15)
C7—C8	1.495 (4)	F5—Si1	1.6677 (16)
C7—H7A	0.9700	F6—Si1	1.6915 (16)
C7—H7B	0.9700	F7—Si2	1.6848 (14)
C8—C9	1.507 (4)	F8—Si2	1.6858 (16)
C8—H8A	0.9700	F9—Si2	1.6741 (15)
C8—H8B	0.9700	F10—Si3	1.6848 (17)
C9—C9i	1.506 (5)	F11—Si3	1.6830 (14)
C9—H9A	0.9700	F12—Si3	1.6759 (14)
C9—H9B	0.9700	Si2—F9iii	1.6741 (15)
C10—N4	1.465 (3)	Si2—F7iii	1.6849 (14)
C10—C11	1.489 (4)	Si2—F8iii	1.6858 (16)
C10—H10A	0.9700	Si3—F12iv	1.6760 (14)
C10—H10B	0.9700	Si3—F11iv	1.6830 (14)
C11—C12	1.508 (4)	Si3—F10iv	1.6848 (17)
C11—H11A	0.9700
N1—C1—C2	112.6 (3)	H12A—C12—H12B	107.6
N1—C1—H1A	109.1	C1—N1—H1NB	109.5
C2—C1—H1A	109.1	C1—N1—H1NA	109.5
N1—C1—H1B	109.1	H1NB—N1—H1NA	109.5
C2—C1—H1B	109.1	C1—N1—H1NC	109.5
H1A—C1—H1B	107.8	H1NB—N1—H1NC	109.5
C3—C2—C1	112.9 (3)	H1NA—N1—H1NC	109.5
C3—C2—H2A	109.0	C6—N2—H2NA	109.5
C1—C2—H2A	109.0	C6—N2—H2NC	109.5
C3—C2—H2B	109.0	H2NA—N2—H2NC	109.5
C1—C2—H2B	109.0	C6—N2—H2NB	109.5
H2A—C2—H2B	107.8	H2NA—N2—H2NB	109.5
C2—C3—C4	115.1 (3)	H2NC—N2—H2NB	109.5
C2—C3—H3A	108.5	C7—N3—H3NA	109.5
C4—C3—H3A	108.5	C7—N3—H3NB	109.5
C2—C3—H3B	108.5	H3NA—N3—H3NB	109.5
C4—C3—H3B	108.5	C7—N3—H3NC	109.5
H3A—C3—H3B	107.5	H3NA—N3—H3NC	109.5
C5—C4—C3	116.0 (3)	H3NB—N3—H3NC	109.5
C5—C4—H4A	108.3	C10—N4—H4NA	109.5
C3—C4—H4A	108.3	C10—N4—H4NB	109.5
C5—C4—H4B	108.3	H4NA—N4—H4NB	109.5
C3—C4—H4B	108.3	C10—N4—H4NC	109.5
H4A—C4—H4B	107.4	H4NA—N4—H4NC	109.5
C4—C5—C6	117.4 (3)	H4NB—N4—H4NC	109.5
C4—C5—H5A	108.0	F5—Si1—F1	91.67 (8)
C6—C5—H5A	108.0	F5—Si1—F3	91.24 (10)
C4—C5—H5B	108.0	F1—Si1—F3	91.04 (9)
C6—C5—H5B	108.0	F5—Si1—F2	179.11 (10)
H5A—C5—H5B	107.2	F1—Si1—F2	88.89 (8)
N2—C6—C5	114.0 (3)	F3—Si1—F2	89.43 (9)
N2—C6—H6A	108.8	F5—Si1—F4	89.45 (8)
C5—C6—H6A	108.8	F1—Si1—F4	178.85 (9)
N2—C6—H6B	108.8	F3—Si1—F4	89.17 (9)
C5—C6—H6B	108.8	F2—Si1—F4	89.98 (8)
H6A—C6—H6B	107.6	F5—Si1—F6	88.99 (9)
N3—C7—C8	112.4 (2)	F1—Si1—F6	89.33 (8)
N3—C7—H7A	109.1	F3—Si1—F6	179.56 (10)
C8—C7—H7A	109.1	F2—Si1—F6	90.33 (9)
N3—C7—H7B	109.1	F4—Si1—F6	90.46 (8)
C8—C7—H7B	109.1	F9iii—Si2—F9	180.0
H7A—C7—H7B	107.9	F9iii—Si2—F7	89.15 (8)
C7—C8—C9	115.8 (3)	F9—Si2—F7	90.85 (8)
C7—C8—H8A	108.3	F9iii—Si2—F7iii	90.85 (8)
C9—C8—H8A	108.3	F9—Si2—F7iii	89.15 (8)
C7—C8—H8B	108.3	F7—Si2—F7iii	180.0
C9—C8—H8B	108.3	F9iii—Si2—F8	90.78 (9)
H8A—C8—H8B	107.4	F9—Si2—F8	89.22 (9)
C9i—C9—C8	112.9 (3)	F7—Si2—F8	89.29 (8)
C9i—C9—H9A	109.0	F7iii—Si2—F8	90.71 (8)
C8—C9—H9A	109.0	F9iii—Si2—F8iii	89.22 (9)
C9i—C9—H9B	109.0	F9—Si2—F8iii	90.78 (9)
C8—C9—H9B	109.0	F7—Si2—F8iii	90.71 (8)
H9A—C9—H9B	107.8	F7iii—Si2—F8iii	89.29 (8)
N4—C10—C11	112.4 (2)	F8—Si2—F8iii	180.0
N4—C10—H10A	109.1	F12—Si3—F12iv	180.0
C11—C10—H10A	109.1	F12—Si3—F11iv	89.08 (8)
N4—C10—H10B	109.1	F12iv—Si3—F11iv	90.92 (8)
C11—C10—H10B	109.1	F12—Si3—F11	90.92 (8)
H10A—C10—H10B	107.8	F12iv—Si3—F11	89.08 (8)
C10—C11—C12	113.3 (3)	F11iv—Si3—F11	180.000 (1)
C10—C11—H11A	108.9	F12—Si3—F10iv	89.24 (9)
C12—C11—H11A	108.9	F12iv—Si3—F10iv	90.76 (9)
C10—C11—H11B	108.9	F11iv—Si3—F10iv	90.66 (9)
C12—C11—H11B	108.9	F11—Si3—F10iv	89.34 (9)
H11A—C11—H11B	107.7	F12—Si3—F10	90.76 (9)
C12ii—C12—C11	114.8 (3)	F12iv—Si3—F10	89.24 (9)
C12ii—C12—H12A	108.6	F11iv—Si3—F10	89.34 (9)
C11—C12—H12A	108.6	F11—Si3—F10	90.66 (9)
C12ii—C12—H12B	108.6	F10iv—Si3—F10	180.00 (12)
C11—C12—H12B	108.6

D—H···A	D—H	H···A	D···A	D—H···A
N2—H2NC···F5	0.89	2.31	3.062 (3)	142
N2—H2NC···F6	0.89	2.27	3.063 (3)	148
N2—H2NB···F7	0.89	2.52	3.095 (3)	123
N2—H2NB···F8	0.89	2.03	2.917 (3)	175
N3—H3NA···F1	0.89	2.06	2.934 (3)	169
N4—H4NA···F8	0.89	2.34	3.095 (3)	143
N4—H4NA···F9	0.89	2.14	2.923 (3)	146
N4—H4NC···F6	0.89	2.00	2.885 (3)	172
N1—H1NB···F11i	0.89	2.07	2.895 (3)	155
N1—H1NA···F10v	0.89	2.01	2.869 (3)	163
N1—H1NC···F2vi	0.89	2.02	2.857 (2)	155
N2—H2NA···F7vii	0.89	2.02	2.906 (3)	170
N3—H3NB···F10iv	0.89	2.48	3.239 (3)	144
N3—H3NB···F12	0.89	2.13	2.907 (2)	145
N3—H3NC···F3viii	0.89	2.02	2.904 (3)	170
N3—H3NC···F4viii	0.89	2.44	3.034 (3)	124
N4—H4NB···F4viii	0.89	2.01	2.832 (3)	154
N4—H4NB···F5viii	0.89	2.51	3.086 (3)	123

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N2—H2NC⋯F5	0.89	2.31	3.062 (3)	142
N2—H2NC⋯F6	0.89	2.27	3.063 (3)	148
N2—H2NB⋯F7	0.89	2.52	3.095 (3)	123
N2—H2NB⋯F8	0.89	2.03	2.917 (3)	175
N3—H3NA⋯F1	0.89	2.06	2.934 (3)	169
N4—H4NA⋯F8	0.89	2.34	3.095 (3)	143
N4—H4NA⋯F9	0.89	2.14	2.923 (3)	146
N4—H4NC⋯F6	0.89	2.00	2.885 (3)	172
N1—H1NB⋯F11i	0.89	2.07	2.895 (3)	155
N1—H1NA⋯F10iii	0.89	2.01	2.869 (3)	163
N1—H1NC⋯F2ii	0.89	2.02	2.857 (2)	155
N2—H2NA⋯F7iv	0.89	2.02	2.906 (3)	170
N3—H3NB⋯F10v	0.89	2.48	3.239 (3)	144
N3—H3NB⋯F12	0.89	2.13	2.907 (2)	145
N3—H3NC⋯F3vi	0.89	2.02	2.904 (3)	170
N3—H3NC⋯F4vi	0.89	2.44	3.034 (3)	124
N4—H4NB⋯F4vi	0.89	2.01	2.832 (3)	154
N4—H4NB⋯F5vi	0.89	2.51	3.086 (3)	123

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) ; (vi) .