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Literature DB >> 24523131

Transition-metal-free catalytic reduction of carbon dioxide.

Frédéric-Georges Fontaine¹, Marc-André Courtemanche, Marc-André Légaré.

Abstract

Metal-free systems, including frustrated Lewis pairs (FLPs) have been shown to bind CO2. By reducing the Lewis acidity and basicity of the ambiphilic system, it is possible to generate active catalysts for the deoxygenative hydroboration of carbon dioxide to methanol derivatives with conversion rates comparable to those of transition-metal-based catalysts.

Entities: Chemical Disease

Keywords: carbon dioxide; frustrated Lewis pairs; main group elements; organocatalysis; reduction

Year: 2014 PMID： 24523131 DOI： 10.1002/chem.201304376

Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236

Keyword Cloud
Cited

8 in total

1. Attempted synthesis of ortho-phenylene phosphino-tritylium cations.

Authors: Kantapat Chansaenpak; Mengxi Yang; François P Gabbaï
Journal: Philos Trans A Math Phys Eng Sci Date: 2017-08-28 Impact factor: 4.226

2. Insight into catalytic reduction of CO₂ to methane with silanes using Brookhart's cationic Ir(iii) pincer complex.

Authors: Shaoqin Fang; Hongcai Chen; Haiyan Wei
Journal: RSC Adv Date: 2018-03-02 Impact factor: 4.036

Review 3. Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

Authors: Amit Kumar; Prosenjit Daw; David Milstein
Journal: Chem Rev Date: 2021-11-02 Impact factor: 60.622

4. Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO₂ in the Presence of Silylhalides.

Authors: Tongtong Wang; Maotong Xu; Andrew R Jupp; Zheng-Wang Qu; Stefan Grimme; Douglas W Stephan
Journal: Angew Chem Int Ed Engl Date: 2021-11-03 Impact factor: 16.823

5. Fluorinated antimony(v) derivatives: strong Lewis acidic properties and application to the complexation of formaldehyde in aqueous solutions.

Authors: Daniel Tofan; François P Gabbaï
Journal: Chem Sci Date: 2016-07-11 Impact factor: 9.825

6. Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO₂, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

Authors: Yu Lu; Zhong-Hua Gao; Xiang-Yu Chen; Jiandong Guo; Zheyuan Liu; Yanfeng Dang; Song Ye; Zhi-Xiang Wang
Journal: Chem Sci Date: 2017-09-11 Impact factor: 9.825

7. Transforming atmospheric CO₂ into alternative fuels: a metal-free approach under ambient conditions.

Authors: Samaresh Chandra Sau; Rameswar Bhattacharjee; Pradip Kumar Hota; Pavan K Vardhanapu; Gonela Vijaykumar; R Govindarajan; Ayan Datta; Swadhin K Mandal
Journal: Chem Sci Date: 2018-11-30 Impact factor: 9.825

Review 8. From CO₂ activation to catalytic reduction: a metal-free approach.

Authors: Sreejyothi P; Swadhin K Mandal
Journal: Chem Sci Date: 2020-08-20 Impact factor: 9.825

8 in total

Transition-metal-free catalytic reduction of carbon dioxide.

1. Attempted synthesis of ortho-phenylene phosphino-tritylium cations.

2. Insight into catalytic reduction of CO2 to methane with silanes using Brookhart's cationic Ir(iii) pincer complex.

Review 3. Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

4. Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO2 in the Presence of Silylhalides.

5. Fluorinated antimony(v) derivatives: strong Lewis acidic properties and application to the complexation of formaldehyde in aqueous solutions.

6. Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO2, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

7. Transforming atmospheric CO2 into alternative fuels: a metal-free approach under ambient conditions.

Review 8. From CO2 activation to catalytic reduction: a metal-free approach.

2. Insight into catalytic reduction of CO₂ to methane with silanes using Brookhart's cationic Ir(iii) pincer complex.

4. Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO₂ in the Presence of Silylhalides.

6. Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO₂, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

7. Transforming atmospheric CO₂ into alternative fuels: a metal-free approach under ambient conditions.

Review 8. From CO₂ activation to catalytic reduction: a metal-free approach.