| Literature DB >> 24520865 |
Aude Carboni1, Guillaume Dagousset, Emmanuel Magnier, Géraldine Masson.
Abstract
A photoredox-catalzyed trifluoromethylation of enecarbamates process is reported. This pathway uses Togni's reagent as the CF3 source and follows a radical/cationic pathway. Under the optimized conditions using [Ru(bpy)3(PF6)2] as the photocatalyst, a wide range of substituted enecarbamates can readily be difunctionalized by means of various O, N, and C nucleophiles.Entities:
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Year: 2014 PMID： 24520865 DOI： 10.1021/ol500374e
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005