| Literature DB >> 24519930 |
Tomoaki Nishida1, Aiko Fukazawa, Eriko Yamaguchi, Hiroya Oshima, Shigehiro Yamaguchi, Motomu Kanai, Yoichiro Kuninobu.
Abstract
Pyridine N-oxide-BF2CF3 and -BF2C2F5 complexes and their derivatives were synthesized. Most of the complexes show fluorescence both in solution and in the solid state. By expanding the π-conjugated skeleton, the color of the fluorescence could be changed dramatically. A fluorophore with a high solvent dependency could also be produced. Since such compounds can be synthesized on a gram scale in high yield, and are stable to oxygen, water, and heat, the complexes hold great potential as organic functional materials.Entities:
Keywords: Lewis acid-base interaction; boranes; charge transfer; fluorescence; pyridine N-oxide
Mesh:
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Year: 2014 PMID: 24519930 DOI: 10.1002/asia.201301688
Source DB: PubMed Journal: Chem Asian J ISSN: 1861-471X