Literature DB >> 24519930

Synthesis of pyridine N-oxide-BF₂CF₃ complexes and their fluorescence properties.

Tomoaki Nishida1, Aiko Fukazawa, Eriko Yamaguchi, Hiroya Oshima, Shigehiro Yamaguchi, Motomu Kanai, Yoichiro Kuninobu.   

Abstract

Pyridine N-oxide-BF2CF3 and -BF2C2F5 complexes and their derivatives were synthesized. Most of the complexes show fluorescence both in solution and in the solid state. By expanding the π-conjugated skeleton, the color of the fluorescence could be changed dramatically. A fluorophore with a high solvent dependency could also be produced. Since such compounds can be synthesized on a gram scale in high yield, and are stable to oxygen, water, and heat, the complexes hold great potential as organic functional materials.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Lewis acid-base interaction; boranes; charge transfer; fluorescence; pyridine N-oxide

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Substances:

Year:  2014        PMID: 24519930     DOI: 10.1002/asia.201301688

Source DB:  PubMed          Journal:  Chem Asian J        ISSN: 1861-471X


  2 in total

1.  Photophysical properties and application in live cell imaging of B,B-fluoro-perfluoroalkyl BODIPYs.

Authors:  Atsuhiko Taniguchi; Taka Sawazaki; Yusuke Shimizu; Youhei Sohma; Motomu Kanai
Journal:  Medchemcomm       Date:  2019-03-16       Impact factor: 3.597

2.  Experimental and Theoretical Examination of the Radical Cations Obtained from the Chemical and Electrochemical Oxidation of 5-Aminothiazoles.

Authors:  Kirara Yamaguchi; Toshiaki Murai; Shoichi Kutsumizu; Yohei Miwa; Masahiro Ebihara; Jing-Dong Guo; Norihiro Tokitoh
Journal:  ChemistryOpen       Date:  2017-03-15       Impact factor: 2.911

  2 in total

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