| Literature DB >> 24497432 |
Wen-Yang Gao1, Yao Chen, Youhong Niu, Kia Williams, Lindsay Cash, Pastor J Perez, Lukasz Wojtas, Jianfeng Cai, Yu-Sheng Chen, Shengqian Ma.
Abstract
Crystal engineering of the nbo metal-organic framework (MOF) platform MOF-505 with a custom-designed azamacrocycle ligand (1,4,7,10-tetrazazcyclododecane-N,N',N'',N'''-tetra-p-methylbenzoic acid) leads to a high density of well-oriented Lewis active sites within the cuboctahedral cage in MMCF-2, [Cu2(Cu-tactmb)(H2O)3(NO3)2]. This MOF demonstrates high catalytic activity for the chemical fixation of CO2 into cyclic carbonates at room temperature under 1 atm pressure.Entities:
Keywords: carbon dioxide; chemical fixation; crystal engineering; metal-organic frameworks; nbo topology
Year: 2014 PMID： 24497432 DOI： 10.1002/anie.201309778
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336