Durability and integrity studies of environmentally conditioned interfaces in fibrous polymeric composites: critical concepts and comments.

Fibre reinforced polymer (FRP) composites are the most promising and elegant material of the present century. Their durability and integrity in various service environments can be altered by the response of its constituent i.e. fibre, polymer matrix, and the existing interface/interphase between the fibre and polymer matrix, in that particular environment. The interphase is generally manifested by chemical bonding, molecular segregation and also by van der Waals bonding. The sizing of fibres generally influences the chemistry and character of the interface/interphase and might generate structural gradient in the polymer matrix. Their susceptibilities to degradation are dependent of the nature of environments and each of the constituents' responds differently and uniquely. Amongst the three constituents, the interface/interphase has a very critical role to play on the performance and reliability of FRP composites. The reduced glass transition temperature of the interphase may induce low modulus area, which subsequently affects fracture toughness and local stresses of the composite. These result in high fracture toughness at ambient temperatures, but significantly reduced performance at high temperatures.