Literature DB >> 24481068

Environmental control of nucleophilic catalysis in water.

Geetika Chadha1, Yan Zhao.   

Abstract

The nucleophilic catalysis by a pyridyl group in ester/phosphate ester hydrolysis was modulated by the microenvironmental hydrophobicity around the catalyst. The catalytic efficiency was enhanced thousands or tens of thousands of times and the activity was maintained well below the pKa of the pyridyl group.

Entities:  

Year:  2014        PMID： 24481068     DOI： 10.1039/c3cc49593k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  pH-Controlled Nanoparticle Catalysts for Highly Selective Tandem Henry Reaction from Mixtures.

Authors:  Ishani Bose; Yan Zhao
Journal:  ACS Catal       Date:  2020-11-17       Impact factor: 13.084

2.  Tunable Artificial Enzyme-Cofactor Complex for Selective Hydrolysis of Acetals.

Authors:  Ishani Bose; Shixin Fa; Yan Zhao
Journal:  J Org Chem       Date:  2021-01-04       Impact factor: 4.354

3.  Surface-Cross-Linked Micelles as Multifunctionalized Organic Nanoparticles for Controlled Release, Light Harvesting, and Catalysis.

Authors:  Yan Zhao
Journal:  Langmuir       Date:  2016-06-01       Impact factor: 3.882

4.  Synthetic glycosidases for the precise hydrolysis of oligosaccharides and polysaccharides.

Authors:  Xiaowei Li; Yan Zhao
Journal:  Chem Sci       Date:  2020-11-05       Impact factor: 9.825
  4 in total

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