Literature DB >> 24478140

Intercalation-controlled cyclodehydration of sorbitol in water over layered-niobium-molybdate solid acid.

Yuya Morita1, Shogo Furusato, Atsushi Takagaki, Shigenobu Hayashi, Ryuji Kikuchi, S Ted Oyama.   

Abstract

Layered niobium molybdate (HNbMoO6 ) was used in the aqueous-phase dehydration of sorbitol and was found to exhibit remarkable selectivity toward its monomolecular-dehydrated intermediate 1,4-sorbitan. This was attributed to the selective intercalation of sorbitol within the interlayers with strong Brønsted acid sites.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  heterogeneous catalysis; intercalations; kinetics; layered compounds; renewable resources

Mesh:

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Year:  2014        PMID: 24478140     DOI: 10.1002/cssc.201300946

Source DB:  PubMed          Journal:  ChemSusChem        ISSN: 1864-5631            Impact factor:   8.928


  3 in total

Review 1.  Isosorbide and dimethyl carbonate: a green match.

Authors:  Fabio Aricò; Pietro Tundo
Journal:  Beilstein J Org Chem       Date:  2016-10-26       Impact factor: 2.883

Review 2.  Chemocatalytic value addition of glucose without carbon-carbon bond cleavage/formation reactions: an overview.

Authors:  Saikat Dutta; Navya Subray Bhat
Journal:  RSC Adv       Date:  2022-02-09       Impact factor: 3.361

3.  Highly active and durable WO3/Al2O3 catalysts for gas-phase dehydration of polyols.

Authors:  Takeshi Aihara; Katsuya Asazuma; Hiroki Miura; Tetsuya Shishido
Journal:  RSC Adv       Date:  2020-10-12       Impact factor: 3.361

  3 in total

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