Literature DB >> 24473703

The cobalt corrole catalyzed hydrogen evolution reaction: surprising electronic effects and characterization of key reaction intermediates.

Atif Mahammed1, Biswajit Mondal, Atanu Rana, Abhishek Dey, Zeev Gross.   

Abstract

A surprising effect of halide substituents on reduction potentials and catalytic activity of halogenated cobalt corroles has been deduced by experimental and computational methods; the proton-activating cobalt(I) and the cobalt(II) corrole that is formed in the step during which hydrogen is formed are characterized by NMR spectroscopy.

Entities:  

Year:  2014        PMID: 24473703     DOI: 10.1039/c3cc48462a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  9 in total

1.  A bi-functional cobalt-porphyrinoid electrocatalyst: balance between overpotential and selectivity.

Authors:  Sk Amanullah; Abhishek Dey
Journal:  J Biol Inorg Chem       Date:  2019-05-30       Impact factor: 3.358

2.  Electronic effects on polypyridyl Co complex-based water reduction catalysts.

Authors:  Xusheng Guo; Chao Li; Weibo Wang; Baowen Zhang; Yuanjun Hou; Xuesong Wang; Qianxiong Zhou
Journal:  RSC Adv       Date:  2021-07-12       Impact factor: 4.036

3.  Photophysical properties and singlet oxygen generation of meso-iodinated free-base corroles.

Authors:  Fang Zhao; Xuan Zhan; Shu-Hui Lai; Lei Zhang; Hai-Yang Liu
Journal:  RSC Adv       Date:  2019-04-24       Impact factor: 4.036

4.  Recent Developments in Hydrogen Evolving Molecular Cobalt(II)-Polypyridyl Catalysts.

Authors:  N Queyriaux; R T Jane; J Massin; V Artero; M Chavarot-Kerlidou
Journal:  Coord Chem Rev       Date:  2015-12-01       Impact factor: 22.315

5.  Synthesis, Characterization, and Reactivity of Functionalized Trinuclear Iron-Sulfur Clusters - A New Class of Bioinspired Hydrogenase Models.

Authors:  Manuel Kaiser; Günther Knör
Journal:  Eur J Inorg Chem       Date:  2015-08-07       Impact factor: 2.524

6.  Understanding light-driven H2 evolution through the electronic tuning of aminopyridine cobalt complexes.

Authors:  Arnau Call; Federico Franco; Noufal Kandoth; Sergio Fernández; María González-Béjar; Julia Pérez-Prieto; Josep M Luis; Julio Lloret-Fillol
Journal:  Chem Sci       Date:  2017-12-19       Impact factor: 9.825

7.  The synthesis and characterization of the octahedral CoIII complex of a pyrrolopyrrolizine derivative formed with dicyanovinylene-bis-(meso-aryl)dipyrrin.

Authors:  Ji-Young Shin
Journal:  RSC Adv       Date:  2021-01-08       Impact factor: 3.361

Review 8.  Metal Complexes of Singly, Doubly and Triply Linked Porphyrins and Corroles: An Insight into the Physicochemical Properties.

Authors:  Arijit Singha Hazari; Shubhadeep Chandra; Sanjib Kar; Biprajit Sarkar
Journal:  Chemistry       Date:  2022-03-07       Impact factor: 5.020

9.  Singly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen-Evolution Reaction.

Authors:  Yongzhen Han; Huayi Fang; Huize Jing; Huiling Sun; Haitao Lei; Wenzhen Lai; Rui Cao
Journal:  Angew Chem Int Ed Engl       Date:  2016-03-30       Impact factor: 15.336

  9 in total

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