Literature DB >> 24471159

Unusual activation of H2 by reduced cobalt complexes supported by a PNP pincer ligand.

Sergio S Rozenel1, Rosa Padilla, Clément Camp, John Arnold.   

Abstract

The reactivity of cobalt complexes supported by a PNP pincer ligand towards H2 varies depending on whether the N-donor atom is protonated; the synthesis of [(HPNP)CoCl(H)2] (2), [(PNP)CoH]2 (4), and the trihydride species [(HPNP)CoH3] (7) (HPNP = HN(CH2CH2P(i)Pr2)2) are described.

Entities:  

Year:  2014        PMID： 24471159     DOI： 10.1039/c3cc46018e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Oxidative Addition of Dihydrogen, Boron Compounds, and Aryl Halides to a Cobalt(I) Cation Supported by a Strong-Field Pincer Ligand.

Authors:  Stephan M Rummelt; Hongyu Zhong; Nadia G Léonard; Scott P Semproni; Paul J Chirik
Journal:  Organometallics       Date:  2019-02-20       Impact factor: 3.876

2.  Synthesis and Reactivity of Four- and Five-Coordinate Low-Spin Cobalt(II) PCP Pincer Complexes and Some Nickel(II) Analogues.

Authors:  Sathiyamoorthy Murugesan; Berthold Stöger; Maria Deus Carvalho; Liliana P Ferreira; Ernst Pittenauer; Günter Allmaier; Luis F Veiros; Karl Kirchner
Journal:  Organometallics       Date:  2014-10-09       Impact factor: 3.876

3.  Synthesis and reactivity of a PCcarbeneP cobalt(i) complex: the missing link in the cobalt PXP pincer series (X = B, C, N).

Authors:  Simon Sung; Qingyang Wang; Tobias Krämer; Rowan D Young
Journal:  Chem Sci       Date:  2018-09-06       Impact factor: 9.825

Review 4.  Ester Hydrogenation with Bifunctional Metal-NHC Catalysts: Recent Advances.

Authors:  Madhusudan K Pandey; Joyanta Choudhury
Journal:  ACS Omega       Date:  2020-11-23

5.  Photo-Initiated Cobalt-Catalyzed Radical Olefin Hydrogenation.

Authors:  Sier Sang; Tobias Unruh; Serhiy Demeshko; Luis I Domenianni; Nicolaas P van Leest; Philipp Marquetand; Felix Schneck; Christian Würtele; Felix J de Zwart; Bas de Bruin; Leticia González; Peter Vöhringer; Sven Schneider
Journal:  Chemistry       Date:  2021-07-20       Impact factor: 5.020
  5 in total

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