Literature DB >> 24454041

Rubidium penta-aqua-(l-serine)cobalt(II) hexa-hydrogenhexa-molybdocobaltate(III) l-serine monosolvate deca-hydrate.

Jun Iijima1, Haruo Naruke2, Hiroshi Takiyama3.   

Abstract

The Co(2+) ion in the title compound, Rb[Co(C3H7NO3)(H2O)5][H6CoMo6O24]·C3H7NO3·10H2O, is coordinated by five water mol-ecules and one O-monodentate l-serine ligand in a slightly distorted octahedral geometry. The Rb(+) ion is irregularly coordinated by nine O atoms. In the crystal, the [H6Co(III)Mo6O24](3-) polyanions are stacked along the b-axis direction, mediated by bridging Rb-O bonds. N-H⋯O and O-H⋯O hydrogen bonds are observed involving the l-serine mol-ecules.

Entities:  

Year:  2013        PMID： 24454041      PMCID： PMC3884265          DOI： 10.1107/S1600536813028304

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN： 1600-5368


Related literature

For background to polyoxidometallates (POMs), see: Hasenknopf et al. (2008 ▶); Du et al. (2013 ▶); Fang et al. (2005 ▶); Kortz et al. (2002 ▶); Sadakane et al. (2001 ▶); Tan et al. (2007 ▶); Inoue & Yamase (1995 ▶). For C—O bond lengths in carboxyl­ates, see: Lide (2007 ▶). For bond-valence sums, see: Brown (1980 ▶). For protonation of POMs, see: Perloff (1970 ▶); Honda et al. (2007 ▶); Yang et al. (2013 ▶). For chiral POMs constructed from an Anderson-type POM as a building block, see: An et al. (2008 ▶).

Experimental

Crystal data

Rb[Co(C3H7NO3)(H2O)5][H6CoMo6O24]·C3H7NO3·10H2O M = 1649.42 Orthorhombic, a = 10.8411 (5) Å b = 11.5923 (4) Å c = 34.8078 (12) Å V = 4374.4 (3) Å3 Z = 4 Mo Kα radiation μ = 3.63 mm−1 T = 183 K 0.41 × 0.36 × 0.19 mm

Data collection

Rigaku R-AXIS RAPID diffractometer Absorption correction: numerical (NUMABS; Rigaku, 1999 ▶) T min = 0.123, T max = 0.500 70065 measured reflections 10010 independent reflections 9728 reflections with F 2 > 2σ(F 2) R int = 0.062

Refinement

R[F 2 > 2σ(F 2)] = 0.036 wR(F 2) = 0.099 S = 1.04 10010 reflections 559 parameters H-atom parameters constrained Δρmax = 3.61 e Å−3 Δρmin = −1.10 e Å−3 Absolute structure: Flack (1983 ▶), 4426 Friedel pairs Absolute structure parameter: 0.025 (7) Data collection: RAPID-AUTO (Rigaku/MSC, 2002 ▶); cell refinement: RAPID-AUTO; data reduction: RAPID-AUTO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: CrystalStructure (Rigaku, 2010 ▶); software used to prepare material for publication: CrystalStructure. Crystal structure: contains datablock(s) General, I. DOI: 10.1107/S1600536813028304/hb7134sup1.cif Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536813028304/hb7134Isup2.hkl Additional supplementary materials: crystallographic information; 3D view; checkCIF report
Rb[Co(C3H7NO3)(H2O)5][H6CoMo6O24]·C3H7NO3·10H2OF(000) = 3212.00
Mr = 1649.42Dx = 2.504 Mg m−3
Orthorhombic, P212121Mo Kα radiation, λ = 0.71075 Å
Hall symbol: P 2ac 2abCell parameters from 59700 reflections
a = 10.8411 (5) Åθ = 3.0–27.5°
b = 11.5923 (4) ŵ = 3.63 mm−1
c = 34.8078 (12) ÅT = 183 K
V = 4374.4 (3) Å3Platelet, green
Z = 40.41 × 0.36 × 0.19 mm
Rigaku R-AXIS RAPID diffractometer9728 reflections with F2 > 2σ(F2)
Detector resolution: 10.000 pixels mm-1Rint = 0.062
ω scansθmax = 27.5°
Absorption correction: numerical (NUMABS; Rigaku, 1999)h = −14→14
Tmin = 0.123, Tmax = 0.500k = −15→14
70065 measured reflectionsl = −45→45
10010 independent reflections
Refinement on F2Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.036H-atom parameters constrained
wR(F2) = 0.099w = 1/[σ2(Fo2) + (0.0641P)2 + 9.0772P] where P = (Fo2 + 2Fc2)/3
S = 1.04(Δ/σ)max = 0.001
10010 reflectionsΔρmax = 3.61 e Å−3
559 parametersΔρmin = −1.10 e Å−3
0 restraintsAbsolute structure: Flack (1983), 4426 Friedel pairs
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.025 (7)
Secondary atom site location: difference Fourier map
Geometry. ENTER SPECIAL DETAILS OF THE MOLECULAR GEOMETRY
Refinement. Refinement was performed using all reflections. The weighted R-factor (wR) and goodness of fit (S) are based on F2. R-factor (gt) are based on F. The threshold expression of F2 > 2.0 σ(F2) is used only for calculating R-factor (gt).
xyzUiso*/Ueq
Mo10.98964 (4)0.94684 (3)0.207793 (11)0.01204 (9)
Mo20.74633 (3)0.84989 (3)0.159456 (12)0.01213 (9)
Mo30.49911 (3)0.75710 (3)0.205914 (11)0.01245 (9)
Mo40.50288 (4)0.74903 (3)0.301413 (11)0.01297 (9)
Mo50.74159 (3)0.84414 (3)0.349594 (12)0.01364 (9)
Mo60.98220 (4)0.94607 (3)0.303320 (11)0.01208 (9)
Rb10.73248 (5)0.52247 (4)0.145507 (15)0.02399 (11)
Co10.74451 (5)0.84817 (4)0.254347 (19)0.00969 (12)
Co20.67086 (6)0.46834 (6)0.043914 (18)0.01672 (14)
O11.0518 (4)1.0822 (4)0.20918 (11)0.0217 (8)
O21.0846 (4)0.8663 (4)0.17903 (10)0.0212 (8)
O30.8426 (4)0.7691 (3)0.13123 (10)0.0196 (7)
O40.6534 (4)0.9266 (4)0.12866 (10)0.0203 (8)
O50.4363 (4)0.6206 (3)0.20593 (11)0.0205 (8)
O60.4087 (4)0.8391 (4)0.17621 (10)0.0205 (8)
O70.4401 (4)0.6137 (3)0.29822 (11)0.0211 (8)
O80.4089 (4)0.8259 (3)0.33182 (10)0.0181 (8)
O90.6422 (4)0.9134 (4)0.37969 (11)0.0233 (8)
O100.8398 (4)0.7659 (4)0.37805 (10)0.0229 (8)
O111.0744 (3)0.8673 (3)0.33354 (10)0.0174 (7)
O121.0443 (4)1.0825 (3)0.30257 (11)0.0200 (8)
O130.8528 (3)0.9780 (3)0.17385 (9)0.0140 (7)
O140.6360 (3)0.7246 (3)0.17290 (10)0.0146 (7)
O150.4347 (3)0.8152 (3)0.25403 (10)0.0156 (7)
O160.6406 (4)0.7154 (3)0.33395 (10)0.0172 (7)
O170.8416 (3)0.9759 (3)0.33605 (10)0.0166 (7)
O181.0544 (3)0.8863 (3)0.25617 (10)0.0143 (7)
O190.8487 (3)0.7967 (3)0.29521 (9)0.0122 (7)
O200.8484 (3)0.9818 (3)0.25489 (9)0.0120 (6)
O210.8514 (3)0.7968 (3)0.21394 (9)0.0109 (7)
O220.6412 (3)0.9013 (3)0.21348 (9)0.0117 (7)
O230.6387 (3)0.7160 (3)0.25320 (10)0.0130 (6)
O240.6384 (3)0.8976 (3)0.29495 (9)0.0124 (7)
O251.0441 (4)0.5935 (4)0.04817 (12)0.0314 (10)
O261.2444 (4)0.5865 (4)0.06457 (11)0.0256 (8)
O271.1876 (4)0.8681 (4)0.06784 (11)0.0254 (8)
O280.7536 (3)0.3482 (3)0.08204 (10)0.0184 (7)
O290.9125 (4)0.2885 (4)0.04575 (11)0.0243 (8)
O300.7725 (4)0.0466 (4)0.05742 (11)0.0334 (10)
O310.7102 (3)0.5053 (3)0.23535 (11)0.0208 (8)
O320.5473 (4)0.5398 (4)0.08612 (11)0.0229 (8)
O330.5412 (4)0.3362 (4)0.03548 (11)0.0247 (8)
O340.7917 (4)0.4190 (4)−0.00155 (10)0.0216 (8)
O350.7958 (4)0.5901 (4)0.06412 (11)0.0243 (8)
O360.5870 (4)0.5650 (4)0.00168 (11)0.0316 (10)
O370.6585 (4)0.2721 (4)−0.04481 (11)0.0275 (9)
O380.2036 (4)0.6949 (4)0.2567 (2)0.0565 (18)
O390.9618 (4)−0.2655 (4)−0.09497 (11)0.0265 (9)
O400.8044 (4)0.0929 (4)−0.01818 (11)0.0250 (9)
O411.3218 (5)1.0091 (4)0.12069 (12)0.0361 (10)
O420.2127 (4)0.6982 (4)−0.04824 (14)0.0353 (10)
O430.5376 (5)0.1397 (4)0.08536 (14)0.0382 (11)
O440.3835 (4)0.6982 (4)0.01085 (12)0.0326 (10)
O450.4649 (5)0.9210 (4)0.02937 (13)0.0389 (11)
N11.2151 (5)0.6988 (4)0.13015 (12)0.0201 (9)
N20.7690 (4)0.1719 (4)0.13211 (14)0.0199 (9)
C11.1344 (5)0.6185 (5)0.06875 (15)0.0201 (10)
C21.1089 (5)0.7005 (5)0.10294 (14)0.0178 (10)
C31.0849 (6)0.8225 (5)0.08854 (16)0.0240 (11)
C40.8428 (5)0.2819 (5)0.07428 (13)0.0170 (10)
C50.8689 (5)0.1813 (5)0.10152 (15)0.0193 (10)
C60.8809 (6)0.0683 (5)0.07916 (16)0.0253 (12)
H11.03370.67270.11680.0214*
H21.01150.82210.07160.0288*
H130.69410.16420.12060.0238*
H120.76930.23670.14690.0238*
H140.78390.10920.14720.0238*
H31.06680.87320.11070.0288*
H41.24970.87000.08230.0305*
H51.19810.74490.15060.0241*
H61.28390.72510.11800.0241*
H71.22820.62540.13840.0241*
H80.94920.19660.11470.0231*
H90.95280.07280.06170.0304*
H100.89500.00390.09730.0304*
H110.7805−0.01570.04530.0401*
U11U22U33U12U13U23
Mo10.00991 (17)0.01256 (18)0.01365 (17)−0.00216 (14)0.00079 (14)0.00013 (14)
Mo20.01080 (18)0.01307 (19)0.01252 (18)−0.00066 (15)−0.00029 (13)0.00023 (13)
Mo30.00977 (18)0.01192 (18)0.01566 (18)−0.00179 (15)−0.00060 (14)−0.00069 (14)
Mo40.01106 (18)0.01205 (18)0.01579 (18)−0.00148 (15)0.00241 (15)0.00050 (14)
Mo50.01245 (19)0.01610 (19)0.01237 (18)0.00063 (16)0.00120 (13)−0.00002 (14)
Mo60.00996 (17)0.01245 (18)0.01384 (18)−0.00125 (14)−0.00103 (14)−0.00076 (14)
Rb10.0239 (3)0.0221 (3)0.0259 (3)0.0034 (2)−0.00233 (19)−0.0013 (2)
Co10.0077 (3)0.0092 (3)0.0121 (3)0.0002 (2)0.0003 (2)−0.0001 (2)
Co20.0147 (3)0.0177 (3)0.0177 (3)0.0013 (3)0.0006 (3)0.0017 (3)
O10.0194 (18)0.0199 (18)0.0257 (19)−0.0014 (15)0.0031 (15)0.0068 (16)
O20.0160 (17)0.029 (2)0.0191 (18)0.0003 (15)0.0028 (14)−0.0047 (16)
O30.0191 (18)0.0188 (17)0.0210 (17)0.0008 (15)−0.0011 (14)−0.0049 (15)
O40.0196 (18)0.0209 (17)0.0204 (17)−0.0006 (15)−0.0066 (14)0.0056 (15)
O50.0197 (18)0.0162 (16)0.0257 (19)−0.0058 (14)0.0034 (15)−0.0026 (15)
O60.0161 (17)0.027 (2)0.0188 (17)0.0060 (16)−0.0053 (14)0.0008 (16)
O70.0223 (19)0.0164 (17)0.0246 (19)−0.0067 (15)−0.0016 (16)0.0025 (15)
O80.0188 (18)0.0186 (18)0.0170 (17)0.0014 (14)0.0040 (14)0.0021 (15)
O90.0195 (18)0.030 (2)0.0208 (18)−0.0012 (15)0.0054 (15)−0.0027 (16)
O100.0213 (18)0.030 (2)0.0174 (18)0.0017 (16)−0.0018 (15)0.0075 (16)
O110.0159 (16)0.0191 (18)0.0174 (17)0.0009 (14)−0.0011 (13)0.0013 (15)
O120.0177 (18)0.0194 (17)0.0228 (18)0.0024 (14)0.0017 (15)0.0010 (15)
O130.0140 (15)0.0110 (15)0.0169 (16)−0.0037 (13)−0.0031 (13)0.0025 (13)
O140.0139 (16)0.0130 (15)0.0168 (16)−0.0049 (13)0.0029 (13)−0.0019 (14)
O150.0102 (14)0.0157 (15)0.0209 (17)0.0005 (11)0.0018 (14)0.0014 (14)
O160.0189 (18)0.0165 (17)0.0164 (17)0.0017 (14)0.0010 (13)0.0024 (14)
O170.0148 (16)0.0171 (17)0.0179 (16)0.0012 (14)0.0000 (13)−0.0055 (14)
O180.0099 (14)0.0153 (15)0.0178 (16)0.0010 (11)−0.0008 (13)−0.0011 (14)
O190.0120 (15)0.0107 (15)0.0139 (16)0.0004 (12)0.0012 (12)0.0006 (13)
O200.0105 (14)0.0095 (13)0.0161 (15)0.0002 (11)0.0004 (12)−0.0011 (13)
O210.0072 (14)0.0104 (14)0.0152 (16)−0.0005 (11)0.0016 (12)−0.0014 (13)
O220.0095 (15)0.0098 (15)0.0159 (16)−0.0007 (12)−0.0020 (12)0.0007 (13)
O230.0108 (14)0.0098 (13)0.0184 (16)−0.0018 (11)0.0014 (13)−0.0002 (14)
O240.0108 (15)0.0109 (15)0.0154 (16)−0.0013 (12)0.0018 (13)0.0016 (13)
O250.022 (2)0.041 (3)0.031 (3)−0.0027 (17)−0.0023 (17)−0.0115 (19)
O260.0184 (18)0.0302 (19)0.028 (2)0.0011 (16)0.0004 (16)−0.0045 (17)
O270.0224 (19)0.029 (2)0.0243 (19)−0.0013 (16)−0.0044 (16)0.0040 (17)
O280.0178 (17)0.0171 (17)0.0203 (17)0.0046 (15)−0.0001 (13)−0.0011 (13)
O290.0192 (18)0.030 (2)0.0237 (19)0.0063 (15)0.0047 (15)0.0074 (17)
O300.044 (3)0.028 (2)0.028 (2)−0.014 (2)0.0039 (18)−0.0053 (18)
O310.0145 (16)0.0127 (16)0.035 (2)0.0019 (13)−0.0039 (14)−0.0001 (15)
O320.0158 (16)0.0253 (19)0.0276 (19)0.0024 (15)0.0028 (14)−0.0021 (16)
O330.0200 (18)0.0232 (18)0.031 (2)−0.0027 (15)−0.0017 (15)0.0007 (17)
O340.0203 (18)0.0229 (17)0.0217 (18)0.0000 (15)0.0020 (14)−0.0005 (15)
O350.0225 (19)0.0197 (18)0.031 (2)−0.0033 (14)0.0032 (16)−0.0035 (16)
O360.026 (2)0.042 (3)0.028 (2)0.0136 (19)0.0042 (16)0.0127 (19)
O370.0190 (18)0.040 (3)0.0231 (19)−0.0027 (17)−0.0008 (15)−0.0048 (18)
O380.0155 (19)0.0092 (17)0.145 (6)0.0025 (14)0.003 (3)−0.008 (3)
O390.0219 (19)0.029 (2)0.0283 (19)0.0050 (17)0.0029 (15)−0.0050 (17)
O400.023 (2)0.027 (2)0.025 (2)−0.0047 (15)−0.0025 (15)−0.0065 (16)
O410.050 (3)0.027 (2)0.031 (3)0.010 (2)−0.007 (2)−0.0032 (19)
O420.034 (3)0.027 (2)0.045 (3)−0.0032 (18)0.005 (2)−0.0022 (19)
O430.034 (3)0.033 (3)0.047 (3)0.0042 (19)0.000 (2)0.010 (2)
O440.028 (3)0.037 (3)0.032 (3)0.0086 (18)0.0041 (18)0.0043 (19)
O450.034 (3)0.044 (3)0.039 (3)0.015 (2)0.003 (2)0.006 (2)
N10.028 (3)0.017 (2)0.016 (2)0.0029 (17)−0.0006 (17)0.0017 (17)
N20.0127 (19)0.0080 (16)0.039 (3)0.0054 (15)0.0093 (18)0.0129 (18)
C10.019 (3)0.021 (3)0.020 (3)0.003 (2)0.0010 (19)−0.003 (2)
C20.016 (3)0.019 (3)0.018 (3)0.0013 (18)0.0034 (19)0.001 (2)
C30.026 (3)0.022 (3)0.024 (3)0.010 (2)0.003 (2)0.007 (3)
C40.017 (3)0.019 (3)0.015 (2)−0.0000 (19)−0.0012 (18)−0.0021 (19)
C50.015 (3)0.020 (3)0.023 (3)0.0019 (19)0.0035 (19)0.006 (2)
C60.028 (3)0.020 (3)0.028 (3)0.009 (3)0.008 (3)0.001 (3)
Mo1—O11.709 (4)Rb1—O283.002 (4)
Mo1—O21.713 (4)Rb1—O313.143 (4)
Mo1—O131.931 (4)Rb1—O322.889 (4)
Mo1—O181.955 (4)Rb1—O353.018 (4)
Mo1—O202.280 (3)Co1—O191.912 (4)
Mo1—O212.306 (3)Co1—O201.915 (3)
Mo2—O31.712 (4)Co1—O211.917 (4)
Mo2—O41.719 (4)Co1—O221.913 (4)
Mo2—O131.946 (4)Co1—O231.915 (3)
Mo2—O141.939 (4)Co1—O241.910 (4)
Mo2—O212.296 (4)Co2—O282.123 (4)
Mo2—O222.278 (4)Co2—O322.154 (4)
Mo3—O51.722 (4)Co2—O332.099 (4)
Mo3—O61.713 (4)Co2—O342.132 (4)
Mo3—O141.914 (4)Co2—O352.078 (4)
Mo3—O151.936 (4)Co2—O362.060 (5)
Mo3—O222.288 (3)O25—C11.248 (7)
Mo3—O232.286 (4)O26—C11.257 (7)
Mo4—Mo53.2749 (6)O27—C31.428 (7)
Mo4—O71.713 (4)O28—C41.264 (6)
Mo4—O81.718 (4)O29—C41.250 (6)
Mo4—O151.964 (4)O30—C61.420 (7)
Mo4—O161.914 (4)N1—C21.491 (7)
Mo4—O232.265 (4)N2—C51.523 (7)
Mo4—O242.275 (4)C1—C21.548 (8)
Mo5—O91.704 (4)C2—C31.523 (8)
Mo5—O101.713 (4)C4—C51.529 (7)
Mo5—O161.929 (4)C5—C61.530 (8)
Mo5—O171.931 (4)O27—H40.840
Mo5—O192.288 (4)O30—H110.840
Mo5—O242.292 (4)N1—H50.910
Mo6—O111.714 (4)N1—H60.910
Mo6—O121.719 (4)N1—H70.910
Mo6—O171.934 (4)N2—H130.910
Mo6—O181.946 (4)N2—H120.910
Mo6—O192.274 (4)N2—H140.910
Mo6—O202.262 (3)C2—H11.000
Rb1—O33.138 (4)C3—H20.990
Rb1—O8i2.858 (4)C3—H30.990
Rb1—O11ii2.855 (4)C5—H81.000
Rb1—O12ii3.099 (4)C6—H90.990
Rb1—O142.737 (4)C6—H100.990
Co1···O133.390 (4)O7···H12v3.2919
Co1···O143.387 (4)O7···H14v3.0848
Co1···O153.380 (3)O8···H13v2.7395
Co1···O163.364 (4)O8···H12v2.3132
Co1···O173.374 (4)O8···H14v3.3485
Co1···O183.389 (3)O10···H8iii2.4384
Co2···O293.349 (4)O11···H12iii2.3729
O1···O123.252 (6)O11···H14iii3.4299
O1···O19iii2.714 (5)O11···H8iii2.6886
O1···O31iii3.344 (6)O13···H13vi3.3249
O2···O33.305 (5)O13···H12vi3.2702
O2···O6iv3.528 (5)O13···H14vi1.9329
O4···O63.287 (5)O13···H8vi3.4279
O4···O7v3.494 (6)O13···H10vi2.7195
O4···O30vi3.122 (6)O25···H12.5619
O4···N2vi3.110 (6)O25···H22.7950
O4···C6vi3.427 (7)O26···H13.0852
O5···O73.214 (6)O26···H43.3433
O5···O24i2.710 (5)O26···H53.5492
O5···O313.414 (5)O26···H62.4944
O7···O22i2.647 (5)O26···H72.6156
O7···N2v3.387 (6)O27···H13.2887
O8···O93.194 (6)O27···H53.2180
O8···N2v2.912 (6)O27···H62.6237
O9···O32v2.789 (6)O28···H132.6015
O10···O113.202 (5)O28···H122.6064
O10···C5iii3.383 (7)O28···H143.5942
O11···N2iii3.073 (6)O28···H82.9795
O11···C4iii3.476 (6)O29···H82.6561
O11···C5iii3.184 (7)O29···H92.5982
O12···O21iii2.790 (5)O30···H132.7231
O13···N2vi2.827 (6)O30···H143.2090
O13···C5vi3.453 (6)O30···H83.2665
O13···C6vi3.472 (7)O36···H9ix3.0878
O15···O31v2.731 (5)N1···H23.3264
O18···O31iii2.915 (5)N1···H32.6702
O23···O312.637 (5)N1···H42.6186
O25···C33.036 (7)N2···H93.3613
O26···O273.323 (6)N2···H102.6694
O26···N12.647 (6)C1···H22.7114
O26···C33.342 (7)C1···H33.3743
O27···N12.940 (6)C1···H43.2060
O27···C12.950 (7)C1···H53.2783
O28···N22.691 (6)C1···H62.6629
O28···C63.528 (7)C1···H72.6307
O29···O303.215 (6)C2···H42.5901
O29···O33vii3.469 (6)C3···H52.6429
O29···O342.592 (6)C3···H62.6418
O29···C62.826 (7)C3···H73.2631
O30···N22.978 (6)C4···H132.6571
O30···C42.893 (7)C4···H122.7012
O33···C43.593 (6)C4···H143.2938
O34···C43.130 (6)C4···H92.7369
O1···O38v3.283 (6)C4···H103.3691
O2···O38iv3.594 (7)C5···H113.1558
O2···N12.944 (6)C6···H132.7233
O2···C23.283 (6)C6···H123.2912
O2···C33.190 (7)C6···H142.6329
O3···O42viii3.236 (6)H1···H22.3511
O3···C23.152 (7)H1···H32.3608
O3···C33.081 (7)H1···H43.4866
O4···O39ix3.030 (6)H1···H52.2942
O4···O42viii3.216 (6)H1···H62.7796
O4···O43vi3.154 (6)H1···H72.3045
O5···O383.198 (7)H2···H42.6673
O6···O39ix3.009 (6)H2···H53.5292
O6···O41x2.916 (6)H2···H63.5481
O6···N1x3.101 (6)H13···H82.7983
O7···O383.091 (7)H13···H102.9751
O9···O26iii3.050 (6)H13···H113.4765
O10···O37xi2.721 (6)H12···H82.2966
O10···O41ii3.455 (6)H12···H103.4808
O13···O38v3.541 (7)H14···H82.3477
O14···O39ix3.339 (6)H14···H93.5184
O15···O382.869 (5)H14···H102.4393
O16···O41ii2.894 (6)H3···H42.2173
O16···O43v3.520 (6)H3···H52.4834
O17···N1iii2.905 (6)H3···H62.9242
O17···C2iii3.403 (6)H3···H73.4992
O18···O38iv2.746 (5)H4···H52.8423
O20···O38v2.566 (5)H4···H62.1224
O25···O352.749 (6)H4···H73.4521
O25···O45viii2.837 (7)H8···H92.3377
O26···O9ii3.050 (6)H8···H102.3876
O26···O32iv3.411 (6)H9···H112.2061
O26···O39vii3.313 (6)H10···H112.2058
O26···O40vii2.713 (6)Mo1···H33.5841
O26···O44iv2.729 (6)Mo5···H7iii3.3029
O27···O34viii3.562 (6)O2···H13.1673
O27···O36viii2.766 (6)O2···H32.3869
O27···O39vii3.337 (6)O2···H52.1144
O27···O412.859 (6)O2···H63.4440
O27···O44iv3.511 (6)O2···H73.4959
O27···O45iv3.347 (6)O3···H12.4073
O28···O433.367 (6)O3···H22.8346
O29···O37vii2.758 (6)O3···H32.8059
O29···O403.386 (6)O5···H5x3.5281
O30···O402.708 (6)O5···H7x3.2581
O30···O42vii2.928 (6)O6···H5x2.6821
O30···O432.931 (7)O6···H6x2.7716
O32···O26x3.411 (6)O6···H7x3.4202
O32···O39ix2.793 (6)O9···H7iii2.9001
O33···O373.159 (6)O12···H1iii3.1126
O33···O40ix2.762 (6)O13···H33.4190
O33···O432.864 (6)O17···H1iii3.1189
O34···O27xii3.562 (6)O17···H5iii3.1826
O34···O372.693 (6)O17···H6iii3.5719
O34···O45viii2.812 (6)O17···H7iii2.0891
O35···O252.749 (6)O27···H9vi3.4869
O35···O42viii2.672 (6)O35···H13.3071
O36···O27xii2.766 (6)O35···H23.5739
O36···O42viii3.467 (6)O36···H2xii2.9821
O36···O442.711 (6)O36···H4xii3.4952
O36···C3xii3.401 (7)O37···H8ix3.3473
O37···O10xiii2.721 (6)O37···H9ix2.9248
O37···O29ix2.758 (6)O38···H12v3.4037
O37···O333.159 (6)O38···H14v3.4937
O37···O342.693 (6)O39···H4ix2.6354
O37···O402.770 (6)O39···H5ix3.4609
O38···O1i3.283 (6)O39···H6ix2.1396
O38···O2x3.594 (7)O39···H7ix3.3673
O38···O53.198 (7)O40···H93.2207
O38···O73.091 (7)O40···H112.5578
O38···O13i3.541 (7)O41···H33.2008
O38···O152.869 (5)O41···H42.2367
O38···O18x2.746 (5)O41···H53.5017
O38···O20i2.566 (5)O41···H63.3191
O39···O4vii3.030 (6)O42···H2xii3.3487
O39···O6vii3.009 (6)O42···H10ix3.5090
O39···O14vii3.339 (6)O42···H11ix2.2422
O39···O26ix3.313 (6)O43···H132.1120
O39···O27ix3.337 (6)O43···H123.4863
O39···O32vii2.793 (6)O43···H143.4463
O39···O41ix3.328 (6)O43···H113.4813
O39···O42xiv3.197 (6)O44···H2xii3.1971
O39···O44vii3.147 (6)O44···H4x3.4995
O39···O45vii2.909 (6)O44···H11ix3.0896
O39···N1ix3.041 (6)O45···H4x3.0294
O40···O26ix2.713 (6)O45···H11vi3.5431
O40···O293.386 (6)C3···H9vi3.3681
O40···O302.708 (6)C3···H10vi2.9592
O40···O33vii2.762 (6)C6···H2xvii3.1970
O40···O372.770 (6)C6···H3xvii3.2224
O40···O44vii3.491 (6)H1···O23.1673
O40···C1ix3.536 (7)H1···O32.4073
O40···C63.500 (7)H1···O12ii3.1126
O41···O6iv2.916 (6)H1···O17ii3.1189
O41···O10iii3.455 (6)H1···O353.3071
O41···O16iii2.894 (6)H2···O32.8346
O41···O272.859 (6)H2···O353.5739
O41···O39vii3.328 (6)H2···O36viii2.9821
O41···O43xv3.046 (7)H2···O42viii3.3487
O41···C33.539 (8)H2···O44viii3.1971
O42···O3xii3.236 (6)H2···C6vi3.1970
O42···O4xii3.216 (6)H2···H9vi2.9953
O42···O30ix2.928 (6)H2···H10vi2.6152
O42···O35xii2.672 (6)H2···H11vi3.2630
O42···O36xii3.467 (6)H13···O432.1120
O42···O39xvi3.197 (6)H12···O38i3.4037
O42···O442.768 (7)H12···O433.4863
O42···O45xii3.092 (7)H14···O38i3.4937
O43···O4xvii3.154 (6)H14···O433.4463
O43···O16i3.520 (6)H3···Mo13.5841
O43···O283.367 (6)H3···O22.3869
O43···O302.931 (7)H3···O32.8059
O43···O332.864 (6)H3···O133.4190
O43···O41xviii3.046 (7)H3···O413.2008
O43···O45xvii3.294 (7)H3···C6vi3.2224
O43···N23.013 (7)H3···H9vi3.1293
O44···O26x2.729 (6)H3···H10vi2.4462
O44···O27x3.511 (6)H4···O36viii3.4952
O44···O362.711 (6)H4···O39vii2.6354
O44···O39ix3.147 (6)H4···O412.2367
O44···O40ix3.491 (6)H4···O44iv3.4995
O44···O422.768 (7)H4···O45iv3.0294
O44···O452.805 (7)H5···O22.1144
O44···C1x3.494 (7)H5···O5iv3.5281
O45···O25xii2.837 (7)H5···O6iv2.6821
O45···O27x3.347 (6)H5···O17ii3.1826
O45···O34xii2.812 (6)H5···O39vii3.4609
O45···O39ix2.909 (6)H5···O413.5017
O45···O42viii3.092 (7)H6···O23.4440
O45···O43vi3.294 (7)H6···O6iv2.7716
O45···O442.805 (7)H6···O17ii3.5719
N1···O22.944 (6)H6···O39vii2.1396
N1···O6iv3.101 (6)H6···O413.3191
N1···O17ii2.905 (6)H7···Mo5ii3.3029
N1···O39vii3.041 (6)H7···O23.4959
N2···O433.013 (7)H7···O5iv3.2581
C1···O40vii3.536 (7)H7···O6iv3.4202
C1···O44iv3.494 (7)H7···O9ii2.9001
C2···O23.283 (6)H7···O17ii2.0891
C2···O33.152 (7)H7···O39vii3.3673
C2···O17ii3.403 (6)H8···O37vii3.3473
C3···O23.190 (7)H9···O27xvii3.4869
C3···O33.081 (7)H9···O37vii2.9248
C3···O36viii3.401 (7)H9···O403.2207
C3···O413.539 (8)H9···C3xvii3.3681
C6···O403.500 (7)H9···H2xvii2.9953
Mo2···H14vi3.0638H9···H3xvii3.1293
Mo2···H10vi3.2343H10···O42vii3.5090
Mo4···H13v3.5913H10···C3xvii2.9592
Mo4···H12v3.4589H10···H2xvii2.6152
Rb1···H123.3372H10···H3xvii2.4462
O3···H10vi3.0200H11···O402.5578
O4···H13vi2.8030H11···O42vii2.2422
O4···H14vi2.6260H11···O433.4813
O4···H10vi2.9750H11···O44vii3.0896
O4···H11vi3.2797H11···O45xvii3.5431
O7···H13v3.2320H11···H2xvii3.2630
O1—Mo1—O2106.26 (19)O12ii—Rb1—O28121.37 (10)
O1—Mo1—O1398.55 (16)O12ii—Rb1—O3159.59 (10)
O1—Mo1—O1899.41 (16)O12ii—Rb1—O32160.80 (11)
O1—Mo1—O2094.66 (15)O12ii—Rb1—O35108.16 (10)
O1—Mo1—O21161.17 (15)O14—Rb1—O28149.48 (10)
O2—Mo1—O13101.91 (16)O14—Rb1—O3171.23 (10)
O2—Mo1—O1895.28 (16)O14—Rb1—O3285.65 (11)
O2—Mo1—O20157.08 (15)O14—Rb1—O35101.05 (11)
O2—Mo1—O2191.95 (15)O28—Rb1—O31134.06 (9)
O13—Mo1—O18150.50 (14)O28—Rb1—O3264.74 (10)
O13—Mo1—O2083.71 (13)O28—Rb1—O3557.77 (10)
O13—Mo1—O2172.44 (13)O31—Rb1—O32131.53 (10)
O18—Mo1—O2071.68 (12)O31—Rb1—O35165.42 (10)
O18—Mo1—O2183.28 (12)O32—Rb1—O3557.89 (11)
O20—Mo1—O2168.32 (11)O19—Co1—O2084.13 (14)
O3—Mo2—O4106.40 (17)O19—Co1—O2195.27 (14)
O3—Mo2—O13101.74 (16)O19—Co1—O22179.37 (14)
O3—Mo2—O1496.02 (16)O19—Co1—O2396.87 (14)
O3—Mo2—O2191.44 (14)O19—Co1—O2484.19 (14)
O3—Mo2—O22157.18 (15)O20—Co1—O2184.43 (13)
O4—Mo2—O1396.50 (16)O20—Co1—O2295.24 (13)
O4—Mo2—O14100.17 (16)O20—Co1—O23178.98 (14)
O4—Mo2—O21160.79 (15)O20—Co1—O2495.97 (14)
O4—Mo2—O2294.94 (15)O21—Co1—O2284.74 (14)
O13—Mo2—O14151.07 (14)O21—Co1—O2395.64 (14)
O13—Mo2—O2172.40 (12)O21—Co1—O24179.29 (14)
O13—Mo2—O2283.38 (13)O22—Co1—O2383.75 (14)
O14—Mo2—O2184.61 (13)O22—Co1—O2495.80 (14)
O14—Mo2—O2271.82 (13)O23—Co1—O2483.96 (14)
O21—Mo2—O2268.69 (11)O28—Co2—O3295.09 (14)
O5—Mo3—O6106.47 (18)O28—Co2—O3383.78 (14)
O5—Mo3—O1497.22 (16)O28—Co2—O3491.63 (14)
O5—Mo3—O15100.19 (16)O28—Co2—O3587.62 (14)
O5—Mo3—O22159.57 (15)O28—Co2—O36171.73 (16)
O5—Mo3—O2394.01 (15)O32—Co2—O3387.67 (15)
O6—Mo3—O14100.99 (16)O32—Co2—O34172.49 (15)
O6—Mo3—O1597.04 (16)O32—Co2—O3585.04 (15)
O6—Mo3—O2292.83 (15)O32—Co2—O3690.17 (16)
O6—Mo3—O23158.31 (15)O33—Co2—O3496.41 (15)
O14—Mo3—O15150.19 (14)O33—Co2—O35168.19 (16)
O14—Mo3—O2272.02 (13)O33—Co2—O3690.08 (16)
O14—Mo3—O2382.99 (13)O34—Co2—O3591.89 (15)
O15—Mo3—O2283.62 (12)O34—Co2—O3683.53 (15)
O15—Mo3—O2371.85 (13)O35—Co2—O3699.20 (17)
O22—Mo3—O2367.91 (11)Mo2—O3—Rb1100.10 (15)
Mo5—Mo4—O7130.93 (13)Mo4—O8—Rb1v154.38 (19)
Mo5—Mo4—O888.76 (12)Mo6—O11—Rb1iii104.41 (16)
Mo5—Mo4—O15126.59 (10)Mo6—O12—Rb1iii95.20 (15)
Mo5—Mo4—O1631.70 (11)Mo1—O13—Mo2118.07 (17)
Mo5—Mo4—O2385.56 (8)Mo2—O14—Mo3118.38 (18)
Mo5—Mo4—O2444.39 (8)Mo2—O14—Rb1108.75 (14)
O7—Mo4—O8106.22 (18)Mo3—O14—Rb1132.38 (16)
O7—Mo4—O1598.85 (16)Mo3—O15—Mo4117.05 (16)
O7—Mo4—O1699.30 (17)Mo4—O16—Mo5116.88 (18)
O7—Mo4—O2393.16 (15)Mo5—O17—Mo6116.42 (18)
O7—Mo4—O24160.57 (16)Mo1—O18—Mo6117.03 (16)
O8—Mo4—O1595.26 (16)Mo5—O19—Mo692.14 (12)
O8—Mo4—O16101.74 (16)Mo5—O19—Co1103.93 (15)
O8—Mo4—O23158.36 (15)Mo6—O19—Co1103.34 (14)
O8—Mo4—O2492.94 (15)Mo1—O20—Mo694.15 (11)
O15—Mo4—O16150.49 (14)Mo1—O20—Co1104.13 (14)
O15—Mo4—O2371.86 (13)Mo6—O20—Co1103.67 (14)
O15—Mo4—O2482.20 (12)Mo1—O21—Mo292.51 (12)
O16—Mo4—O2384.08 (14)Mo1—O21—Co1103.11 (14)
O16—Mo4—O2473.07 (14)Mo2—O21—Co1102.89 (14)
O23—Mo4—O2468.58 (11)Mo2—O22—Mo392.91 (12)
Mo4—Mo5—O988.49 (13)Mo2—O22—Co1103.68 (14)
Mo4—Mo5—O10127.50 (14)Mo3—O22—Co1104.17 (14)
Mo4—Mo5—O1631.42 (11)Mo3—O23—Mo493.89 (11)
Mo4—Mo5—O17125.79 (11)Mo3—O23—Co1104.17 (14)
Mo4—Mo5—O1984.06 (9)Mo4—O23—Co1103.81 (15)
Mo4—Mo5—O2443.98 (8)Mo4—O24—Mo591.63 (12)
O9—Mo5—O10106.67 (18)Mo4—O24—Co1103.59 (14)
O9—Mo5—O16100.31 (17)Mo5—O24—Co1103.84 (15)
O9—Mo5—O1797.62 (17)Rb1—O28—Co289.21 (11)
O9—Mo5—O19160.55 (16)Rb1—O28—C4128.6 (3)
O9—Mo5—O2494.26 (16)Co2—O28—C4126.0 (3)
O10—Mo5—O1696.11 (17)Rb1—O32—Co291.66 (12)
O10—Mo5—O17102.17 (17)Rb1—O35—Co289.61 (13)
O10—Mo5—O1992.05 (15)O25—C1—O26127.5 (5)
O10—Mo5—O24157.81 (15)O25—C1—C2116.4 (5)
O16—Mo5—O17149.46 (15)O26—C1—C2116.1 (5)
O16—Mo5—O1982.45 (14)N1—C2—C1110.0 (4)
O16—Mo5—O2472.42 (13)N1—C2—C3110.7 (4)
O17—Mo5—O1972.73 (13)C1—C2—C3110.3 (5)
O17—Mo5—O2481.81 (13)O27—C3—C2112.1 (5)
O19—Mo5—O2468.03 (12)O28—C4—O29126.5 (5)
O11—Mo6—O12105.70 (18)O28—C4—C5118.2 (4)
O11—Mo6—O17101.14 (16)O29—C4—C5115.3 (5)
O11—Mo6—O1895.36 (15)N2—C5—C4110.9 (4)
O11—Mo6—O1992.39 (15)N2—C5—C6110.8 (4)
O11—Mo6—O20158.22 (15)C4—C5—C6110.7 (5)
O12—Mo6—O1798.83 (16)O30—C6—C5110.6 (5)
O12—Mo6—O1899.02 (16)C3—O27—H4109.473
O12—Mo6—O19161.42 (15)C6—O30—H11109.466
O12—Mo6—O2094.11 (15)C2—N1—H5109.471
O17—Mo6—O18151.34 (14)C2—N1—H6109.455
O17—Mo6—O1973.00 (13)C2—N1—H7109.469
O17—Mo6—O2084.30 (13)H5—N1—H6109.477
O18—Mo6—O1983.13 (13)H5—N1—H7109.484
O18—Mo6—O2072.22 (13)H6—N1—H7109.471
O19—Mo6—O2068.83 (11)C5—N2—H13109.480
O3—Rb1—O8i167.01 (10)C5—N2—H12109.476
O3—Rb1—O11ii109.60 (10)C5—N2—H14109.470
O3—Rb1—O12ii65.85 (10)H13—N2—H12109.468
O3—Rb1—O1454.60 (10)H13—N2—H14109.467
O3—Rb1—O28117.88 (9)H12—N2—H14109.467
O3—Rb1—O31104.15 (9)N1—C2—H1108.575
O3—Rb1—O3295.04 (10)C1—C2—H1108.597
O3—Rb1—O3561.86 (10)C3—C2—H1108.589
O8i—Rb1—O11ii79.66 (10)O27—C3—H2109.176
O8i—Rb1—O12ii115.90 (10)O27—C3—H3109.174
O8i—Rb1—O14112.41 (11)C2—C3—H2109.171
O8i—Rb1—O2872.99 (10)C2—C3—H3109.182
O8i—Rb1—O3168.50 (10)H2—C3—H3107.896
O8i—Rb1—O3283.11 (11)N2—C5—H8108.109
O8i—Rb1—O35126.03 (11)C4—C5—H8108.111
O11ii—Rb1—O12ii54.54 (10)C6—C5—H8108.105
O11ii—Rb1—O14136.93 (11)O30—C6—H9109.516
O11ii—Rb1—O2873.03 (10)O30—C6—H10109.526
O11ii—Rb1—O3176.24 (10)C5—C6—H9109.517
O11ii—Rb1—O32137.42 (11)C5—C6—H10109.524
O11ii—Rb1—O35103.69 (10)H9—C6—H10108.087
O12ii—Rb1—O1484.44 (10)
O1—Mo1—O13—Mo2177.9 (2)O17—Mo5—O19—Co1−88.44 (16)
O1—Mo1—O18—Mo672.4 (2)O19—Mo5—O17—Mo6−21.03 (16)
O1—Mo1—O20—Mo6−83.55 (16)O17—Mo5—O24—Mo4179.52 (14)
O1—Mo1—O20—Co1171.23 (17)O17—Mo5—O24—Co175.09 (16)
O2—Mo1—O13—Mo269.2 (2)O24—Mo5—O17—Mo6−90.48 (19)
O2—Mo1—O18—Mo6179.83 (19)O19—Mo5—O24—Mo4104.90 (13)
O2—Mo1—O20—Mo672.5 (4)O19—Mo5—O24—Co10.47 (12)
O2—Mo1—O20—Co1−32.7 (5)O24—Mo5—O19—Mo6103.84 (13)
O2—Mo1—O21—Mo2−87.70 (15)O24—Mo5—O19—Co1−0.47 (12)
O2—Mo1—O21—Co1168.45 (17)O11—Mo6—O12—Rb1iii3.34 (17)
O13—Mo1—O18—Mo6−54.4 (4)O12—Mo6—O11—Rb1iii−3.73 (19)
O18—Mo1—O13—Mo2−55.1 (4)O11—Mo6—O17—Mo5−68.0 (2)
O13—Mo1—O20—Mo6178.34 (13)O17—Mo6—O11—Rb1iii−106.31 (15)
O13—Mo1—O20—Co173.12 (15)O11—Mo6—O18—Mo1−178.75 (19)
O20—Mo1—O13—Mo2−88.30 (18)O18—Mo6—O11—Rb1iii97.23 (14)
O13—Mo1—O21—Mo214.17 (12)O11—Mo6—O19—Mo585.10 (15)
O13—Mo1—O21—Co1−89.68 (15)O11—Mo6—O19—Co1−170.05 (17)
O21—Mo1—O13—Mo2−19.09 (15)O19—Mo6—O11—Rb1iii−179.45 (13)
O18—Mo1—O20—Mo614.84 (12)O11—Mo6—O20—Mo1−72.3 (4)
O18—Mo1—O20—Co1−90.39 (15)O11—Mo6—O20—Co133.3 (5)
O20—Mo1—O18—Mo6−19.47 (15)O20—Mo6—O11—Rb1iii151.0 (3)
O18—Mo1—O21—Mo2177.21 (13)O12—Mo6—O17—Mo5−176.0 (2)
O18—Mo1—O21—Co173.36 (15)O17—Mo6—O12—Rb1iii107.63 (13)
O21—Mo1—O18—Mo6−88.82 (17)O12—Mo6—O18—Mo1−71.9 (2)
O20—Mo1—O21—Mo2104.29 (13)O18—Mo6—O12—Rb1iii−94.88 (13)
O20—Mo1—O21—Co10.44 (12)O12—Mo6—O20—Mo183.31 (15)
O21—Mo1—O20—Mo6104.78 (13)O12—Mo6—O20—Co1−171.05 (17)
O21—Mo1—O20—Co1−0.45 (12)O20—Mo6—O12—Rb1iii−167.51 (11)
O4—Mo2—O3—Rb1−108.37 (16)O17—Mo6—O18—Mo156.0 (4)
O3—Mo2—O13—Mo1−68.6 (2)O18—Mo6—O17—Mo556.0 (4)
O13—Mo2—O3—Rb1151.16 (12)O17—Mo6—O19—Mo5−15.82 (13)
O3—Mo2—O14—Mo3180.0 (2)O17—Mo6—O19—Co189.03 (16)
O3—Mo2—O14—Rb17.03 (17)O19—Mo6—O17—Mo521.13 (16)
O14—Mo2—O3—Rb1−5.89 (15)O17—Mo6—O20—Mo1−178.21 (14)
O3—Mo2—O21—Mo187.80 (15)O17—Mo6—O20—Co1−72.57 (15)
O3—Mo2—O21—Co1−168.14 (17)O20—Mo6—O17—Mo590.70 (18)
O21—Mo2—O3—Rb178.84 (12)O18—Mo6—O19—Mo5−179.78 (14)
O3—Mo2—O22—Mo3−74.7 (4)O18—Mo6—O19—Co1−74.93 (15)
O3—Mo2—O22—Co130.6 (5)O19—Mo6—O18—Mo189.48 (17)
O22—Mo2—O3—Rb150.2 (4)O18—Mo6—O20—Mo1−14.86 (12)
O4—Mo2—O13—Mo1−176.89 (19)O18—Mo6—O20—Co190.78 (15)
O4—Mo2—O14—Mo3−72.1 (3)O20—Mo6—O18—Mo119.57 (15)
O4—Mo2—O14—Rb1114.93 (16)O19—Mo6—O20—Mo1−104.26 (13)
O4—Mo2—O22—Mo384.66 (15)O19—Mo6—O20—Co11.38 (12)
O4—Mo2—O22—Co1−170.00 (17)O20—Mo6—O19—Mo5−106.23 (13)
O13—Mo2—O14—Mo352.1 (4)O20—Mo6—O19—Co1−1.38 (12)
O13—Mo2—O14—Rb1−120.8 (3)O3—Rb1—O11ii—Mo6ii40.54 (18)
O14—Mo2—O13—Mo158.1 (4)O11ii—Rb1—O3—Mo2−129.20 (14)
O13—Mo2—O21—Mo1−14.06 (12)O3—Rb1—O12ii—Mo6ii−142.79 (18)
O13—Mo2—O21—Co190.00 (15)O12ii—Rb1—O3—Mo2−95.77 (16)
O21—Mo2—O13—Mo119.17 (15)O3—Rb1—O14—Mo2−4.67 (12)
O13—Mo2—O22—Mo3−179.35 (13)O3—Rb1—O14—Mo3−176.3 (3)
O13—Mo2—O22—Co1−74.01 (15)O14—Rb1—O3—Mo25.09 (13)
O22—Mo2—O13—Mo188.87 (18)O3—Rb1—O28—Co2−53.19 (14)
O14—Mo2—O21—Mo1−176.28 (14)O3—Rb1—O28—C484.8 (3)
O14—Mo2—O21—Co1−72.22 (15)O28—Rb1—O3—Mo2150.14 (13)
O21—Mo2—O14—Mo389.09 (19)O31—Rb1—O3—Mo2−49.02 (16)
O21—Mo2—O14—Rb1−83.85 (14)O3—Rb1—O32—Co290.18 (13)
O14—Mo2—O22—Mo3−14.44 (12)O32—Rb1—O3—Mo286.11 (15)
O14—Mo2—O22—Co190.90 (16)O3—Rb1—O35—Co2−156.67 (16)
O22—Mo2—O14—Mo319.78 (17)O35—Rb1—O3—Mo2135.39 (18)
O22—Mo2—O14—Rb1−153.17 (17)O8i—Rb1—O11ii—Mo6ii−130.02 (17)
O21—Mo2—O22—Mo3−105.70 (13)O11ii—Rb1—O8i—Mo4i105.3 (5)
O21—Mo2—O22—Co1−0.35 (12)O8i—Rb1—O12ii—Mo6ii51.42 (18)
O22—Mo2—O21—Mo1−103.71 (13)O12ii—Rb1—O8i—Mo4i63.4 (5)
O22—Mo2—O21—Co10.35 (12)O8i—Rb1—O14—Mo2175.29 (13)
O5—Mo3—O14—Mo2178.2 (2)O8i—Rb1—O14—Mo33.7 (3)
O5—Mo3—O14—Rb1−10.9 (3)O14—Rb1—O8i—Mo4i−31.4 (5)
O5—Mo3—O15—Mo470.6 (2)O8i—Rb1—O28—Co2119.11 (13)
O5—Mo3—O22—Mo275.1 (5)O8i—Rb1—O28—C4−102.9 (3)
O5—Mo3—O22—Co1−29.8 (5)O28—Rb1—O8i—Mo4i−179.4 (5)
O5—Mo3—O23—Mo4−83.85 (15)O31—Rb1—O8i—Mo4i26.2 (4)
O5—Mo3—O23—Co1170.86 (17)O8i—Rb1—O32—Co2−102.75 (13)
O6—Mo3—O14—Mo269.7 (3)O32—Rb1—O8i—Mo4i−113.8 (5)
O6—Mo3—O14—Rb1−119.3 (3)O8i—Rb1—O35—Co211.12 (18)
O6—Mo3—O15—Mo4178.83 (19)O35—Rb1—O8i—Mo4i−155.2 (4)
O6—Mo3—O22—Mo2−86.02 (15)O11ii—Rb1—O12ii—Mo6ii−2.37 (12)
O6—Mo3—O22—Co1169.08 (17)O12ii—Rb1—O11ii—Mo6ii2.44 (13)
O6—Mo3—O23—Mo477.2 (4)O11ii—Rb1—O14—Mo276.3 (2)
O6—Mo3—O23—Co1−28.1 (5)O11ii—Rb1—O14—Mo3−95.3 (3)
O14—Mo3—O15—Mo4−54.2 (4)O14—Rb1—O11ii—Mo6ii−18.2 (3)
O15—Mo3—O14—Mo2−56.4 (4)O11ii—Rb1—O28—Co2−156.80 (13)
O15—Mo3—O14—Rb1114.5 (3)O11ii—Rb1—O28—C4−18.9 (3)
O14—Mo3—O22—Mo214.62 (13)O28—Rb1—O11ii—Mo6ii154.77 (17)
O14—Mo3—O22—Co1−90.28 (16)O31—Rb1—O11ii—Mo6ii−59.83 (15)
O22—Mo3—O14—Mo2−19.67 (17)O11ii—Rb1—O32—Co2−36.2 (2)
O22—Mo3—O14—Rb1151.3 (3)O32—Rb1—O11ii—Mo6ii162.24 (13)
O14—Mo3—O23—Mo4179.36 (14)O11ii—Rb1—O35—Co298.18 (13)
O14—Mo3—O23—Co174.06 (16)O35—Rb1—O11ii—Mo6ii105.17 (16)
O23—Mo3—O14—Mo2−88.66 (19)O12ii—Rb1—O14—Mo259.53 (15)
O23—Mo3—O14—Rb182.3 (2)O12ii—Rb1—O14—Mo3−112.1 (3)
O15—Mo3—O22—Mo2177.20 (14)O14—Rb1—O12ii—Mo6ii163.66 (16)
O15—Mo3—O22—Co172.30 (15)O12ii—Rb1—O28—Co2−130.50 (11)
O22—Mo3—O15—Mo4−89.09 (17)O12ii—Rb1—O28—C47.4 (3)
O15—Mo3—O23—Mo415.57 (12)O28—Rb1—O12ii—Mo6ii−33.72 (19)
O15—Mo3—O23—Co1−89.73 (16)O31—Rb1—O12ii—Mo6ii92.19 (16)
O23—Mo3—O15—Mo4−20.29 (15)O12ii—Rb1—O35—Co2154.91 (11)
O22—Mo3—O23—Mo4105.96 (13)O35—Rb1—O12ii—Mo6ii−96.50 (15)
O22—Mo3—O23—Co10.66 (12)O14—Rb1—O28—Co213.7 (3)
O23—Mo3—O22—Mo2104.23 (13)O14—Rb1—O28—C4151.6 (2)
O23—Mo3—O22—Co1−0.67 (13)O28—Rb1—O14—Mo2−90.3 (3)
O7—Mo4—Mo5—O9−108.32 (17)O28—Rb1—O14—Mo398.1 (3)
O7—Mo4—Mo5—O101.64 (18)O31—Rb1—O14—Mo2119.27 (16)
O7—Mo4—Mo5—O164.43 (17)O31—Rb1—O14—Mo3−52.3 (2)
O7—Mo4—Mo5—O17153.37 (17)O14—Rb1—O32—Co2144.03 (13)
O7—Mo4—Mo5—O1989.66 (17)O32—Rb1—O14—Mo2−104.00 (16)
O7—Mo4—Mo5—O24153.96 (18)O32—Rb1—O14—Mo384.4 (3)
Mo5—Mo4—O8—Rb1v94.4 (5)O14—Rb1—O35—Co2−117.37 (12)
O8—Mo4—Mo5—O92.23 (12)O35—Rb1—O14—Mo2−47.92 (16)
O8—Mo4—Mo5—O10112.20 (12)O35—Rb1—O14—Mo3140.5 (2)
O8—Mo4—Mo5—O16114.98 (12)O31—Rb1—O28—Co2153.09 (10)
O8—Mo4—Mo5—O17−96.07 (12)O31—Rb1—O28—C4−69.0 (3)
O8—Mo4—Mo5—O19−159.78 (12)O28—Rb1—O32—Co2−28.34 (11)
O8—Mo4—Mo5—O24−95.48 (12)O32—Rb1—O28—Co228.78 (11)
Mo5—Mo4—O15—Mo390.33 (17)O32—Rb1—O28—C4166.7 (3)
O15—Mo4—Mo5—O997.86 (12)O28—Rb1—O35—Co238.75 (11)
O15—Mo4—Mo5—O10−152.17 (12)O35—Rb1—O28—Co2−37.80 (11)
O15—Mo4—Mo5—O16−149.39 (12)O35—Rb1—O28—C4100.1 (3)
O15—Mo4—Mo5—O17−0.44 (12)O31—Rb1—O32—Co2−155.87 (10)
O15—Mo4—Mo5—O19−64.15 (12)O32—Rb1—O35—Co2−39.72 (12)
O15—Mo4—Mo5—O240.15 (12)O35—Rb1—O32—Co238.08 (11)
Mo5—Mo4—O16—Mo50.000 (13)O19—Co1—O20—Mo196.40 (14)
O16—Mo4—Mo5—O9−112.8 (2)O19—Co1—O20—Mo6−1.54 (14)
O16—Mo4—Mo5—O10−2.8 (2)O20—Co1—O19—Mo597.16 (14)
O16—Mo4—Mo5—O160.0 (2)O20—Co1—O19—Mo61.53 (14)
O16—Mo4—Mo5—O17148.9 (2)O19—Co1—O21—Mo1−84.05 (14)
O16—Mo4—Mo5—O1985.2 (2)O19—Co1—O21—Mo2−179.76 (14)
O16—Mo4—Mo5—O24149.5 (2)O21—Co1—O19—Mo5−179.00 (14)
Mo5—Mo4—O23—Mo3−146.22 (9)O21—Co1—O19—Mo685.36 (14)
Mo5—Mo4—O23—Co1−40.60 (12)O19—Co1—O23—Mo3179.18 (14)
O23—Mo4—Mo5—O9161.34 (8)O19—Co1—O23—Mo481.48 (15)
O23—Mo4—Mo5—O10−88.70 (9)O23—Co1—O19—Mo5−82.65 (15)
O23—Mo4—Mo5—O16−85.91 (8)O23—Co1—O19—Mo6−178.29 (14)
O23—Mo4—Mo5—O1763.03 (8)O19—Co1—O24—Mo4−95.67 (15)
O23—Mo4—Mo5—O19−0.68 (8)O19—Co1—O24—Mo5−0.53 (14)
O23—Mo4—Mo5—O2463.62 (8)O24—Co1—O19—Mo50.53 (14)
Mo5—Mo4—O24—Mo50.0O24—Co1—O19—Mo6−95.11 (15)
Mo5—Mo4—O24—Co1104.66 (16)O20—Co1—O21—Mo1−0.49 (13)
O24—Mo4—Mo5—O997.71 (12)O20—Co1—O21—Mo2−96.20 (14)
O24—Mo4—Mo5—O10−152.32 (12)O21—Co1—O20—Mo10.50 (14)
O24—Mo4—Mo5—O16−149.54 (12)O21—Co1—O20—Mo6−97.44 (14)
O24—Mo4—Mo5—O17−0.59 (12)O20—Co1—O22—Mo284.29 (14)
O24—Mo4—Mo5—O19−64.30 (12)O20—Co1—O22—Mo3−179.08 (14)
O24—Mo4—Mo5—O240.00 (12)O22—Co1—O20—Mo1−83.68 (14)
O7—Mo4—O8—Rb1v−133.0 (5)O22—Co1—O20—Mo6178.39 (14)
O7—Mo4—O15—Mo3−70.0 (2)O20—Co1—O24—Mo4−179.13 (14)
O7—Mo4—O16—Mo5−176.6 (2)O20—Co1—O24—Mo5−83.98 (14)
O7—Mo4—O23—Mo382.94 (16)O24—Co1—O20—Mo1179.91 (14)
O7—Mo4—O23—Co1−171.43 (17)O24—Co1—O20—Mo681.97 (14)
O8—Mo4—O15—Mo3−177.30 (19)O21—Co1—O22—Mo20.39 (13)
O15—Mo4—O8—Rb1v−32.2 (5)O21—Co1—O22—Mo397.02 (14)
O8—Mo4—O16—Mo5−67.8 (3)O22—Co1—O21—Mo195.31 (14)
O16—Mo4—O8—Rb1v123.6 (5)O22—Co1—O21—Mo2−0.39 (13)
O8—Mo4—O23—Mo3−71.0 (4)O21—Co1—O23—Mo3−84.80 (15)
O8—Mo4—O23—Co134.7 (5)O21—Co1—O23—Mo4177.50 (14)
O23—Mo4—O8—Rb1v19.8 (8)O23—Co1—O21—Mo1178.48 (14)
O8—Mo4—O24—Mo585.21 (15)O23—Co1—O21—Mo282.78 (14)
O8—Mo4—O24—Co1−170.13 (17)O22—Co1—O23—Mo3−0.74 (14)
O24—Mo4—O8—Rb1v50.2 (5)O22—Co1—O23—Mo4−98.44 (15)
O15—Mo4—O16—Mo556.1 (4)O23—Co1—O22—Mo2−95.89 (15)
O16—Mo4—O15—Mo357.4 (4)O23—Co1—O22—Mo30.74 (14)
O15—Mo4—O23—Mo3−15.34 (12)O22—Co1—O24—Mo484.96 (15)
O15—Mo4—O23—Co190.28 (16)O22—Co1—O24—Mo5−179.89 (14)
O23—Mo4—O15—Mo320.49 (15)O24—Co1—O22—Mo2−179.14 (14)
O15—Mo4—O24—Mo5−179.88 (14)O24—Co1—O22—Mo3−82.51 (15)
O15—Mo4—O24—Co1−75.22 (15)O23—Co1—O24—Mo41.89 (14)
O24—Mo4—O15—Mo390.43 (17)O23—Co1—O24—Mo597.04 (15)
O16—Mo4—O23—Mo3−178.02 (14)O24—Co1—O23—Mo395.80 (15)
O16—Mo4—O23—Co1−72.40 (16)O24—Co1—O23—Mo4−1.90 (14)
O23—Mo4—O16—Mo591.14 (19)O28—Co2—O32—Rb137.56 (13)
O16—Mo4—O24—Mo5−16.17 (13)O32—Co2—O28—Rb1−35.90 (12)
O16—Mo4—O24—Co188.49 (17)O32—Co2—O28—C4−175.6 (3)
O24—Mo4—O16—Mo521.76 (17)O33—Co2—O28—Rb1−122.99 (13)
O23—Mo4—O24—Mo5−106.37 (13)O33—Co2—O28—C497.3 (3)
O23—Mo4—O24—Co1−1.71 (13)O34—Co2—O28—Rb1140.73 (12)
O24—Mo4—O23—Mo3−103.91 (13)O34—Co2—O28—C41.0 (3)
O24—Mo4—O23—Co11.71 (13)O28—Co2—O35—Rb1−48.56 (12)
Mo4—Mo5—O16—Mo40.000 (14)O35—Co2—O28—Rb148.91 (13)
Mo4—Mo5—O17—Mo6−90.06 (18)O35—Co2—O28—C4−90.8 (3)
Mo4—Mo5—O19—Mo6146.27 (9)O33—Co2—O32—Rb1121.10 (14)
Mo4—Mo5—O19—Co141.96 (12)O32—Co2—O35—Rb146.77 (13)
Mo4—Mo5—O24—Mo40.0O35—Co2—O32—Rb1−49.60 (13)
Mo4—Mo5—O24—Co1−104.43 (16)O36—Co2—O32—Rb1−148.82 (15)
O9—Mo5—O16—Mo469.6 (3)O34—Co2—O35—Rb1−140.10 (12)
O9—Mo5—O17—Mo6176.3 (2)O36—Co2—O35—Rb1136.14 (13)
O9—Mo5—O24—Mo4−83.39 (16)Rb1—O28—C4—O29−110.3 (5)
O9—Mo5—O24—Co1172.19 (18)Rb1—O28—C4—C571.0 (5)
O10—Mo5—O16—Mo4177.8 (2)Co2—O28—C4—O2913.8 (7)
O10—Mo5—O17—Mo667.3 (3)Co2—O28—C4—C5−164.9 (3)
O10—Mo5—O19—Mo6−86.24 (16)O25—C1—C2—N1165.7 (4)
O10—Mo5—O19—Co1169.46 (18)O25—C1—C2—C3−71.9 (6)
O10—Mo5—O24—Mo477.3 (5)O26—C1—C2—N1−15.5 (6)
O10—Mo5—O24—Co1−27.1 (5)O26—C1—C2—C3106.9 (5)
O16—Mo5—O17—Mo6−58.1 (4)N1—C2—C3—O2761.8 (6)
O17—Mo5—O16—Mo4−55.4 (4)C1—C2—C3—O27−60.2 (6)
O16—Mo5—O19—Mo6177.87 (14)O28—C4—C5—N26.4 (6)
O16—Mo5—O19—Co173.57 (16)O28—C4—C5—C6129.8 (4)
O19—Mo5—O16—Mo4−90.95 (19)O29—C4—C5—N2−172.4 (4)
O16—Mo5—O24—Mo416.10 (13)O29—C4—C5—C6−49.0 (6)
O16—Mo5—O24—Co1−88.33 (17)N2—C5—C6—O3066.2 (5)
O24—Mo5—O16—Mo4−21.67 (17)C4—C5—C6—O30−57.3 (6)
O17—Mo5—O19—Mo615.87 (12)
D—H···AD—HH···AD···AD—H···A
O27—H4···O410.842.242.859 (6)131
O27—H4···N10.842.622.940 (6)104
O30—H11···O400.842.562.708 (6)91
O30—H11···O42vii0.842.242.928 (6)139
N1—H5···O20.912.112.944 (6)151
N1—H6···O260.912.492.647 (6)89
N1—H6···O39vii0.912.143.041 (6)170
N1—H7···O17ii0.912.092.905 (6)149
N2—H13···O280.912.602.691 (6)86
N2—H13···O430.912.113.013 (7)170
N2—H12···O8i0.912.312.912 (6)123
N2—H12···O280.912.612.691 (6)85
N2—H14···O13xvii0.911.932.827 (6)167
Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A D—HH⋯A D⋯A D—H⋯A
O27—H4⋯O410.842.242.859 (6)131
O27—H4⋯N10.842.622.940 (6)104
O30—H11⋯O42i 0.842.242.928 (6)139
N1—H5⋯O20.912.112.944 (6)151
N1—H6⋯O39i 0.912.143.041 (6)170
N1—H7⋯O17ii 0.912.092.905 (6)149
N2—H13⋯O430.912.113.013 (7)170
N2—H12⋯O8iii 0.912.312.912 (6)123
N2—H14⋯O13iv 0.911.932.827 (6)167

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) .

  6 in total

1.  Heteropolymolybdates of AsIII, SbIII, BiIII, SeIV, and TeIV functionalized by amino acids.

Authors:  Ulrich Kortz; Masha G Savelieff; Fida Y Abou Ghali; Lina M Khalil; Samer A Maalouf; Dima I Sinno
Journal:  Angew Chem Int Ed Engl       Date:  2002-11-04       Impact factor: 15.336

2.  Enantiomerically pure polytungstates: chirality transfer through zirconium coordination centers to nanosized inorganic clusters.

Authors:  Xikui Fang; Travis M Anderson; Craig L Hill
Journal:  Angew Chem Int Ed Engl       Date:  2005-06-06       Impact factor: 15.336

3.  Protonation and methylation of an Anderson-type polyoxoanion [IMo6O24]5-.

Authors:  Daisuke Honda; Shusaku Ikegami; Tomoaki Inoue; Tomoji Ozeki; Atsushi Yagasaki
Journal:  Inorg Chem       Date:  2007-01-26       Impact factor: 5.165

4.  Chiral polyoxometalate-induced enantiomerically 3D architectures: a new route for synthesis of high-dimensional chiral compounds.

Authors:  Huaqiao Tan; Yangguang Li; Zhiming Zhang; Chao Qin; Xinlong Wang; Enbo Wang; Zhongmin Su
Journal:  J Am Chem Soc       Date:  2007-07-26       Impact factor: 15.419

5.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

6.  Chiral polyoxotungstates. 1. Stereoselective interaction of amino acids with enantiomers of [Ce(III)(alpha1-P2W17O61)(H2O)x]7-. The structure of DL-[Ce2(H2O)8(P2W17O61)2]14-.

Authors:  M Sadakane; M H Dickman; M T Pope
Journal:  Inorg Chem       Date:  2001-06-04       Impact factor: 5.165
  6 in total

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