Literature DB >> 24454027

[2,6-Di-fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](penta-ne-2,4-dionato-κ(2) O,O')iridium(III).

Kaijun Luo1, Chenyang Zhang1, Juan Jia1, Daibing Luo2.   

Abstract

The title compound, [Ir(C10H5F2N2)2(C5H7O2)], has a distorted octa-hedral coordination geometry around the Ir(III) atom, retaining the cis-C,C/trans-N,N chelate disposition in two 2,6-di-fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl ligands which are nearly mutually perpendicular [dihedral angle = 82.75 (15)°]. The mol-ecular structure is stabilized by weak C-H⋯O and C-H⋯F hydrogen-bond inter-actions. The crystal structure is stabilized by π-π stacking inter-actions (centroid-centroid distance = 3.951 Å).

Entities:  

Year:  2013        PMID: 24454027      PMCID: PMC3884251          DOI: 10.1107/S1600536813026160

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  5 in total

Review 1.  Recent progresses on materials for electrophosphorescent organic light-emitting devices.

Authors:  Lixin Xiao; Zhijian Chen; Bo Qu; Jiaxiu Luo; Sheng Kong; Qihuang Gong; Junji Kido
Journal:  Adv Mater       Date:  2010-10-28       Impact factor: 30.849

2.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

3.  Synthesis and characterization of phosphorescent cyclometalated iridium complexes.

Authors:  S Lamansky; P Djurovich; D Murphy; F Abdel-Razzaq; R Kwong; I Tsyba; M Bortz; B Mui; R Bau; M E Thompson
Journal:  Inorg Chem       Date:  2001-03-26       Impact factor: 5.165

4.  Highly phosphorescent bis-cyclometalated iridium complexes: synthesis, photophysical characterization, and use in organic light emitting diodes.

Authors:  S Lamansky; P Djurovich; D Murphy; F Abdel-Razzaq; H E Lee; C Adachi; P E Burrows; S R Forrest; M E Thompson
Journal:  J Am Chem Soc       Date:  2001-05-09       Impact factor: 15.419

5.  Blue phosphorescent Ir(III) complex with high color purity: fac-tris(2',6'-difluoro-2,3'-bipyridinato-N,C(4'))iridium(III).

Authors:  Seok Jong Lee; Ki-Min Park; Kiyull Yang; Youngjin Kang
Journal:  Inorg Chem       Date:  2009-02-02       Impact factor: 5.165

  5 in total

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