Literature DB >> 24453186

Iron(II)-catalyzed direct cyanation of arenes with aryl(cyano)iodonium triflates.

Zhibin Shu1, Wenzhi Ji, Xi Wang, Yujing Zhou, Yan Zhang, Jianbo Wang.   

Abstract

A direct oxidative cyanation of arenes under Fe(II) catalysis with 3,5-di(trifluoromethyl)phenyl(cyano)iodonium triflate (DFCT) as the cyanating agent has been developed. The reaction is applicable to wide range of aromatic substrates, including polycyclic structures and heteroaromatic compounds.
Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  aromatic substitution; aryl nitriles; cyanation; hypervalent iodine; iron catalysis

Year:  2014        PMID： 24453186     DOI： 10.1002/anie.201309791

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  Direct C-H Cyanation of Arenes via Organic Photoredox Catalysis.

Authors:  Joshua B McManus; David A Nicewicz
Journal:  J Am Chem Soc       Date:  2017-02-14       Impact factor: 15.419

2.  One-pot regioselective C-H activation iodination-cyanation of 2,4-diarylquinazolines using malononitrile as a cyano source.

Authors:  Ziqiao Yan; Banlai Ouyang; Xunchun Mao; Wei Gao; Zhihong Deng; Yiyuan Peng
Journal:  RSC Adv       Date:  2019-06-11       Impact factor: 4.036

Review 3.  Direct cyanation, hydrocyanation, dicyanation and cyanofunctionalization of alkynes.

Authors:  Lifen Peng; Zhifang Hu; Hong Wang; Li Wu; Yinchun Jiao; Zilong Tang; Xinhua Xu
Journal:  RSC Adv       Date:  2020-03-10       Impact factor: 4.036

4.  Iodine(III) Reagents in Radical Chemistry.

Authors:  Xi Wang; Armido Studer
Journal:  Acc Chem Res       Date:  2017-06-21       Impact factor: 22.384

5.  C-H Cyanation of 6-Ring N-Containing Heteroaromatics.

Authors:  Bryony L Elbert; Alistair J M Farley; Timothy W Gorman; Tarn C Johnson; Christophe Genicot; Bénédicte Lallemand; Patrick Pasau; Jakub Flasz; José L Castro; Malcolm MacCoss; Robert S Paton; Christopher J Schofield; Martin D Smith; Michael C Willis; Darren J Dixon
Journal:  Chemistry       Date:  2017-09-22       Impact factor: 5.236

6.  Room temperature decarboxylative cyanation of carboxylic acids using photoredox catalysis and cyanobenziodoxolones: a divergent mechanism compared to alkynylation.

Authors:  Franck Le Vaillant; Matthew D Wodrich; Jérôme Waser
Journal:  Chem Sci       Date:  2016-12-22       Impact factor: 9.825

7.  Metal-Free Direct C-H Cyanation of Alkenes.

Authors:  Xi Wang; Armido Studer
Journal:  Angew Chem Int Ed Engl       Date:  2018-08-06       Impact factor: 15.336

8.  Synthesis of FeIII and FeIV Cyanide Complexes Using Hypervalent Iodine Reagents as Cyano-Transfer One-Electron Oxidants.

Authors:  Charafa Souilah; Sergio A V Jannuzzi; Derya Demirbas; Sergei Ivlev; Marcel Swart; Serena DeBeer; Alicia Casitas
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-29       Impact factor: 16.823
  8 in total

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