Literature DB >> 24446126

Comment on "synthesis, characterization, and structures of persistent aniline radical cation": it is a protonated aniline and not an aniline radical cation.

Marat R Talipov1, Jeewantha S Hewage, Sergey V Lindeman, James R Gardinier, Rajendra Rathore.   

Abstract

The same, but different: The reaction of tri-tert-butylaniline (TBA) with AgSbF6 in CH2 Cl2 produces a green-colored intermediate which undergoes decomposition to form a protonated aniline (TBAH(+) SbF6 (-) ). Crystals of the protonated aniline salt were analyzed by X-ray diffraction and found to have the same crystal characteristics as the crystals of the supposed cation radical first identified in 2012.
Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Jahn-Teller effect; anilines; radical cations; spin contamination

Year:  2013        PMID: 24446126     DOI: 10.1002/anie.201305293

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  2 in total

1.  Two Roomtemperature-stable Trications - Triprotonated Triamino- and Tricyanobenzene.

Authors:  Alexander Nitzer; Robert Hübsch; Christoph Jessen; Andreas J Kornath
Journal:  ChemistryOpen       Date:  2022-05       Impact factor: 2.630

2.  Direct synthesis of 2-oxo-acetamidines from methyl ketones, aromatic amines and DMF via copper-catalyzed C(sp3)-H amidination.

Authors:  Dianke Xie; Wei He; Jiang Xiao; Yao Wu; Yongjia Guo; Qiang Liu; Cancheng Guo
Journal:  RSC Adv       Date:  2019-03-04       Impact factor: 4.036

  2 in total

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