Literature DB >> 24446013

A singly bonded amido-distannyne: H(2) activation and isocyanide coordination.

Terrance J Hadlington1, Cameron Jones.   

Abstract

The first amido-distannyne, L(†)SnSnL(†) (L(†) = -N(Ar(†))(SiPr(i)3), Ar(†) = C6H2{C(H)Ph2}2Pr(i)-2,6,4), has been prepared and shown to possess a very long Sn-Sn single bond; the compound activates dihydrogen under ambient conditions to give L(†)Sn(μ-H)2SnL(†), and reacts with Bu(t)NC to give a stable adduct complex, L(†)(Bu(t)NC)SnSn(CNBu(t))L(†).

Entities:  

Year:  2014        PMID： 24446013     DOI： 10.1039/c3cc49651a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Reduction of organic azides by indyl-anions. Isolation and reactivity studies of indium-nitrogen multiple bonds.

Authors:  Mathew D Anker; Matthias Lein; Martyn P Coles
Journal:  Chem Sci       Date:  2018-11-12       Impact factor: 9.825

2.  Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me3 P)2 (Ph3 P)Rh≡E-Ar*] (E=Sn, Pb).

Authors:  Max Widemann; Klaus Eichele; Hartmut Schubert; Christian P Sindlinger; Steffen Klenner; Rainer Pöttgen; Lars Wesemann
Journal:  Angew Chem Int Ed Engl       Date:  2021-02-01       Impact factor: 15.336

3.  Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C-C bond activation.

Authors:  Joschua Helmer; Olli J Pakkanen; Chris Gendy; Alexander Hepp; Heikki M Tuononen; Felicitas Lips
Journal:  Chem Commun (Camb)       Date:  2022-03-10       Impact factor: 6.222

Review 4.  Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis.

Authors:  Franziska Hanusch; Lisa Groll; Shigeyoshi Inoue
Journal:  Chem Sci       Date:  2020-08-03       Impact factor: 9.825
  4 in total

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