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Literature DB >> 24445933

Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium.

Valeri Leich¹, Thomas P Spaniol, Laurent Maron, Jun Okuda.

Abstract

Bis(triphenylsilyl)calcium [Ca(SiPh3)2(thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C-C double bonds efficiently and regioselectively.

Entities: Chemical

Year: 2014 PMID： 24445933 DOI： 10.1039/c3cc49308c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

3 in total

1. Regioselective Hydrosilylation of Olefins Catalyzed by a Molecular Calcium Hydride Cation.

Authors: Danny Schuhknecht; Thomas P Spaniol; Laurent Maron; Jun Okuda
Journal: Angew Chem Int Ed Engl Date: 2019-11-19 Impact factor: 15.336

2. Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters.

Authors: Nicole L Lampland; Aradhana Pindwal; Steven R Neal; Shealyn Schlauderaff; Arkady Ellern; Aaron D Sadow
Journal: Chem Sci Date: 2015-08-26 Impact factor: 9.825

3. Alkali Metal Triphenyl- and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand.

Authors: Danny Schuhknecht; Valeri Leich; Thomas P Spaniol; Iskander Douair; Laurent Maron; Jun Okuda
Journal: Chemistry Date: 2020-02-18 Impact factor: 5.236

3 in total