Literature DB >> 24441469

Oxovanadium(V)-induced diastereoselective oxidative homocoupling of boron enolates.

Toru Amaya1, Takaya Masuda, Yusuke Maegawa, Toshikazu Hirao.   

Abstract

Oxovanadium(v)-induced dl-selective oxidative coupling of (Z)-boron enolate was demonstrated to give the corresponding 2,3-disubstituted 1,4-diketone in a good yield. High selectivity (up to 94 : 6) was attained when the reaction was performed with VO(OPr-i)2Cl at -30 °C.

Entities:  

Year:  2014        PMID: 24441469     DOI: 10.1039/c3cc49624d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Chemoselective Intermolecular Cross-Enolate-Type Coupling of Amides.

Authors:  Daniel Kaiser; Christopher J Teskey; Pauline Adler; Nuno Maulide
Journal:  J Am Chem Soc       Date:  2017-11-03       Impact factor: 15.419

  1 in total

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