Literature DB >> 24437909

Coherent states formulation of polymer field theory.

Xingkun Man1, Kris T Delaney2, Michael C Villet1, Henri Orland3, Glenn H Fredrickson1.   

Abstract

We introduce a stable and efficient complex Langevin (CL) scheme to enable the first direct numerical simulations of the coherent-states (CS) formulation of polymer field theory. In contrast with Edwards' well-known auxiliary-field (AF) framework, the CS formulation does not contain an embedded nonlinear, non-local, implicit functional of the auxiliary fields, and the action of the field theory has a fully explicit, semi-local, and finite-order polynomial character. In the context of a polymer solution model, we demonstrate that the new CS-CL dynamical scheme for sampling fluctuations in the space of coherent states yields results in good agreement with now-standard AF-CL simulations. The formalism is potentially applicable to a broad range of polymer architectures and may facilitate systematic generation of trial actions for use in coarse-graining and numerical renormalization-group studies.

Entities:  

Year:  2014        PMID: 24437909     DOI: 10.1063/1.4860978

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  2 in total

1.  Direct free energy evaluation of classical and quantum many-body systems via field-theoretic simulation.

Authors:  Glenn H Fredrickson; Kris T Delaney
Journal:  Proc Natl Acad Sci U S A       Date:  2022-04-26       Impact factor: 12.779

Review 2.  Ionic Compatibilization of Polymers.

Authors:  Glenn H Fredrickson; Shuyi Xie; Jerrick Edmund; My Linh Le; Dan Sun; Douglas J Grzetic; Daniel L Vigil; Kris T Delaney; Michael L Chabinyc; Rachel A Segalman
Journal:  ACS Polym Au       Date:  2022-07-22
  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.