| Literature DB >> 24437909 |
Xingkun Man1, Kris T Delaney2, Michael C Villet1, Henri Orland3, Glenn H Fredrickson1.
Abstract
We introduce a stable and efficient complex Langevin (CL) scheme to enable the first direct numerical simulations of the coherent-states (CS) formulation of polymer field theory. In contrast with Edwards' well-known auxiliary-field (AF) framework, the CS formulation does not contain an embedded nonlinear, non-local, implicit functional of the auxiliary fields, and the action of the field theory has a fully explicit, semi-local, and finite-order polynomial character. In the context of a polymer solution model, we demonstrate that the new CS-CL dynamical scheme for sampling fluctuations in the space of coherent states yields results in good agreement with now-standard AF-CL simulations. The formalism is potentially applicable to a broad range of polymer architectures and may facilitate systematic generation of trial actions for use in coarse-graining and numerical renormalization-group studies.Entities:
Year: 2014 PMID: 24437909 DOI: 10.1063/1.4860978
Source DB: PubMed Journal: J Chem Phys ISSN: 0021-9606 Impact factor: 3.488