Filling dynamics of closed end nanocapillaries.

We have studied the filling dynamics of model capillaries using dynamic mean field theory for a confined lattice gas and Kawasaki dynamics simulations. We have found two different scenarios for filling of capped nanocapillaries from the vapor phase. As compared to channels with macroscopic width, in which the filling process occurs by the detachment of the meniscus from the cap, in mesoscopic channels there is an alternative mechanism associated with the spontaneous condensation of the liquid close to the pore opening and its subsequent growth toward the closed pore end. We show that these two scenarios have totally different filling dynamics, providing an additional mechanism for slow capillary condensation kinetics in nanoscopic objects.