Literature DB >> 24432797

Activation of aryl halides at gold(I): practical synthesis of (P,C) cyclometalated gold(III) complexes.

Johannes Guenther1, Sonia Mallet-Ladeira, Laura Estevez, Karinne Miqueu, Abderrahmane Amgoune, Didier Bourissou.   

Abstract

Taking advantage of phosphine chelation, direct evidence for oxidative addition of Csp(2)-X bonds (X = I, Br) to a single gold atom is reported. NMR studies and DFT calculations provide insight into this unprecedented transformation, which gives straightforward access to stable (P,C) cyclometalated gold(III) complexes.

Entities:  

Year:  2014        PMID： 24432797     DOI： 10.1021/ja412432k

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  20 in total

1.  Gold Redox Catalysis with a Selenium Cation as a Mild Oxidant.

Authors:  Jin Wang; Chiyu Wei; Xuming Li; Pengyi Zhao; Chuan Shan; Lukasz Wojtas; Hao Chen; Xiaodong Shi
Journal:  Chemistry       Date:  2020-04-14       Impact factor: 5.236

2.  Gold-catalyzed allylation of aryl boronic acids: accessing cross-coupling reactivity with gold.

Authors:  Mark D Levin; F Dean Toste
Journal:  Angew Chem Int Ed Engl       Date:  2014-05-05       Impact factor: 15.336

3.  Gold Redox Catalysis through Base-Initiated Diazonium Decomposition toward Alkene, Alkyne, and Allene Activation.

Authors:  Boliang Dong; Haihui Peng; Stephen E Motika; Xiaodong Shi
Journal:  Chemistry       Date:  2017-07-24       Impact factor: 5.236

4.  Efficient Computation of Geometries for Gold Complexes.

Authors:  Isaac F Leach; Leonardo Belpassi; Paola Belanzoni; Remco W A Havenith; Johannes E M N Klein
Journal:  Chemphyschem       Date:  2021-05-28       Impact factor: 3.102

5.  Stable gold(III) catalysts by oxidative addition of a carbon-carbon bond.

Authors:  Chung-Yeh Wu; Takahiro Horibe; Christian Borch Jacobsen; F Dean Toste
Journal:  Nature       Date:  2015-01-22       Impact factor: 49.962

6.  Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides.

Authors:  Abdallah Zeineddine; Laura Estévez; Sonia Mallet-Ladeira; Karinne Miqueu; Abderrahmane Amgoune; Didier Bourissou
Journal:  Nat Commun       Date:  2017-09-18       Impact factor: 14.919

7.  Au(iii)-aryl intermediates in oxidant-free C-N and C-O cross-coupling catalysis.

Authors:  Jordi Serra; Teodor Parella; Xavi Ribas
Journal:  Chem Sci       Date:  2016-09-23       Impact factor: 9.825

8.  Controlled Interconversion of a Dinuclear Au Species Supported by a Redox-Active Bridging PNP Ligand Facilitates Ligand-to-Gold Electron Transfer.

Authors:  Vincent Vreeken; Maxime A Siegler; Jarl Ivar van der Vlugt
Journal:  Chemistry       Date:  2017-04-03       Impact factor: 5.236

9.  Gold(iii)-arene complexes by insertion of olefins into gold-aryl bonds.

Authors:  Feriel Rekhroukh; Charlie Blons; Laura Estévez; Sonia Mallet-Ladeira; Karinne Miqueu; Abderrahmane Amgoune; Didier Bourissou
Journal:  Chem Sci       Date:  2017-04-19       Impact factor: 9.825

10.  Suzuki-Miyaura coupling of arylboronic acids to gold(iii).

Authors:  Ayan Maity; Amanda N Sulicz; Nihal Deligonul; Matthias Zeller; Allen D Hunter; Thomas G Gray
Journal:  Chem Sci       Date:  2014-11-06       Impact factor: 9.825
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