Literature DB >> 24427080

2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl di-ethyl-dithio-carbamate.

T G Meenakshi1, H C Devarajegowda2, K Mahesh Kumar3, O Kotresh3, Venkatesh B Devaru4.   

Abstract

In the title compound, C16H17NO3S2, the dihedral angles between the O/C/C/S group and the 2H-chromene ring system and the thio-carbamate group are 14.46 (9) and 83.30 (9)°, respectively. The bond-angle sum at the N atom is 360.0°. One of the methyl C atoms lies above the thio-carbamate plane and one lies below it [deviations = 1.264 (3) and -1.147 (3) Å, respectively]. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds generate R 2 (2)(10) loops. Weak aromatic π-π stacking inter-actions [shortest centroid-centroid distance = 3.8138 (11) Å] are also observed.

Entities:  

Year:  2013        PMID: 24427080      PMCID: PMC3884423          DOI: 10.1107/S1600536813021806

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  2 in total

1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  (5,7-Dimethyl-2-oxo-2H-chromen-4-yl)methyl diethyl-dithio-carbamate.

Authors:  K Mahesh Kumar; H C Devarajegowda; S Jeyaseelan; N M Mahabaleshwaraiah; O Kotresh
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-05-05
  2 in total

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